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| ArticleName | Hydrocarbonyl process of clearing and processing of ammonium salts of hexachloroplatinate and hexachloroiridate |
| ArticleAuthor | Fedoseev I. V. |
| ArticleAuthorData | Fedoseev I. V., e-mail: fn6-kf@bmstukaluga.ru |
| Abstract | Paper shows that at pulp processing (NH4)2PtCl6 by monoxide of carbon at atmospheric pressure and t = 20–90 °C there is a clearing of impurity of a palladium and rare platinoids, and platinum can be received by hydrometallurgical method. Allocation of iridium in the form of an individual product — carbonylchloride from which it is possible to receive a powder of iridium of high cleanliness can be realized by the similar method from mix (NH4)2PtCl6 + (NH4)2IrCl6, polluted by others platinum and nonferrous metals. |
| keywords | Platinum metals, chloride complexes, monoxide of carbon, hydrocarbonylchloration, clearing, concentration, extraction, allocating. |
| References | 1. Skomarokhov V. A., Konik K. P., Lavrov A. A., Bogdanov V. I. // Tsvetnye metally. 2007. № 6. P/ 54-55. 2. Fedosеev I. V. // Platinum Met. Rev. 1996. Vol. 40, N 3. P. 118–125. 3. Fedoseev I. V. // Tsvetnye metally. 2006. № 8. P. 78-82. 4. Spitsyn V. I., Fedoseev I. V. // Dokl. AN USSR. 1977. V. 236, № 6. P. 1415-1417. 5. Spitsyn V. I., Fedoseev I. V. // Zhurn. neorg. Khimii. 1986. V. 31, № 7. P. 1800-1802. 6. Konnik K. P., Gorbachev L. D., Antsygina Yu. N. at al. // Tez. dokl. XVII Mezhdun. soveshchaniya po khimii, analizu i tekhnologii platinovikh metallov – M., 2001. P. 250. |
| Language of full-text | russian |
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