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HEAVY NON-FERROUS METALS
Название Development of an effective technology for hydrometallurgical processing of zinc cakes by Almalyk MMC JSC
DOI 10.17580/tsm.2025.02.04
Автор Yakubov М. М., Kholikulov D. B., Yokubov O. M., Khaidaraliev H. R.
Информация об авторе

Almalyk Branch of the National University of Science and Technology MISIS, Almalyk, Uzbekistan

М. М. Yakubov, Professor of the Department of Metallurgy, Doctor of Technical Sciences, e-mail: yakubovmahmud51@gmail.com

O. M. Ekubov, Associate Professor of the Department of Metallurgy, PhD

 

Almalyk Branch of the Tashkent State Technical University named after Islam Karimov, Almalyk, Uzbekistan
D. B. Kholikulov, Deputy Director for Research and Innovation, Doctor of Technical Sciences, Professor, e-mail: doniyor_xb@mail.ru
H. R. Khaidaraliev, Doctoral Candidate of the Department of Metallurgy

Реферат

Currently, much attention is being paid to the more complete extraction of valuable components of zinc-containing raw materials, the application of waste-free technology, and the production of pure zinc of the highest grade in zinc production. Hydrometallurgy is an effective method of processing zinc concentrates. This method is also used in Almalyk MMC JSC. In accordance with this method, the cinder obtained after the oxidative roasting of zinc sulfide concentrates is subjected to sulfuric acid leaching. In this case, a zinc sulfate solution is formed, which, after purification, is sent to the electrolysis shop to obtain zinc cathode. Also, a solid residue (a recycled product) is formed in the process — zinc cake with a high content of zinc (18–24%) and copper (0.3–1.5%), which are in the form of insoluble ferrites. The main method of cakes processing is the Waelz process. In Almalyk MMC JSC, the Waelz process is carried out in rotary tube furnaces. The disadvantages of the process include the high consumption of imported expensive coke: 492 kg is consumed per 1 ton of cake. In order to exclude the expensive Waelz process, research work has been carried out on the processing of zinc cakes by the hydrometallurgical method. The process of high-temperature sulfuric acid leaching has proven itself well in the processing of zinc cake, ensuring the selectivity and complexity. The optimal mode of the process: the duration of leaching is 4–4.5 hours, the concentration of sulfuric acid is 180–190 g/l, the leaching temperature is 90 oC. The end-to-end extraction of zinc into the solution is 97–98.5%, copper — 92–93%. The obtained sulfuric acid solution contains, g/l: zinc — 53.4; copper — 4.28; iron — 14.8.

Ключевые слова Zinc, cake, leaching, concentrate, extraction, solution, clinker
Библиографический список

1. Marchenko N. V., Olejnikova N. V. Complex processing of mineral, secondary and man-made raw materials of heavy non-ferrous metals. Technologies for the production of heavy non-ferrous metals. Part 1. Metallurgy of lead, zinc and cadmium : textbook. Krasnoyarsk : SibFU, 2018. 278 p.
2. Zaitsev V. Ya., Margulis E. V. Metallurgy of lead and zinc. Moscow : Metallurgiya, 1985. 262 p.
3. Kholikulov D. B., Ruzikulov Q. M., Khaidaraliev K. R. Improving the technology of waelzation of zinc cakes. Mining Journal of Kazakhstan. 2022. No. 6. pp. 23–28.
4. Toshkodirova R. E., Abdurahmonov S. A., Berdiyarov B. T. Research on electromagnetic enrichment of clinker. Universum: technical sciences. 2021. No. 4. Available at: https://7universum.com/ru/tech/archive/item/11571
5. Toshkodirova R. E., Abdurahmonov S. A. Processing of clinker, a manmade waste from zinc production. Universum: technical sciences. 2020. No. 11. Available at: https://7universum.com/ru/tech/archive/item/10966
6. Yakubov M. M., Abdukadyrov A. A., Mukhamedzhanova Sh. A., Ekubov O. M. Inclusion of secondary raw materials in the production circuit at Almalyk MMC. Tsvetnye Metally. 2022. No. 5. pp. 36–40.
7. Yakubov M. M., Dzhumaeva Kh. Yu., Umaraliev I. S., Mukhamedzhanova Sh. A. Understanding the possibility of using secondary raw materials when smelting copper sulphide concentrates in Almalyk MMC’s Vanyukov furnace. Tsvetnye Metally. 2023. No. 5. pp. 14–19.
8. Abdurahmonov S. A., Toshkodirova R. E., Ahmadzhonov U. M., Kurbonov Sh. K. Extraction of valuable components from zinc production waste. Mining Bulletin of Uzbekistan. 2010. No. 2. pp. 83–86.
9. Kolesnikov A. S., Kopsalyamov B. A., Kolesnikova O. R., Kuraev R. M., Stryukovskiy I. A. The technology of processing waste of the zinc industry to produce ferroalloys and fumes of non-ferrous metals. Bulletin of SUSU: Metallurgy. 2013. Vol. 13. No. 1. pp. 34–39.
10. Asimi A., Gharibi K., Abkhoshk E., Moosakazemi F., Chelgani S. C. Effects of operational parameters on the low contaminant jarosite precipitation process-an industrial scale study. Materials (Basel). 2020. Vol. 13, Iss. 20. 4662. DOI: 10.3390/ma13204662
11. Pappu A., Saxena M., Asolekar S. R. Jarosite characteristics and its utilisation potentials. Science of the Total Environment. 2006. Vol. 359, Iss. 1-3. pp. 232–243. DOI: 10.1016/j.scitotenv.2005.04.024
12. Ahtamov F. E., Toshev O. E., Huzhakulov N. B., Erkinov F. F. Automated control of the efficiency of zinc cakes thermal heat treatment. Universum: technical sciences. 2022. No. 8. Available at: https://7universum.com/ru/tech/archive/item/14192
13. Kholikulov D. B., Yakubov M. M., Mukhametdzhanova Sh. A., Bekbutaev A. N. Development of technology for extracting metals from process solutions by ion flotation. Tsvetnye Metally. 2022. No. 6. pp. 19–24.
14. Kholikulov D. B., Matkarimov S. T. Pilot tests of processing technologies of process solutions of copper production by ozonation. MaterialsToday: Proceedings. 2021. Vol. 45. Part 6. pp. 4987–4992. DOI: 10.1016/j.matpr.2021.01.419
15. Kazanbaev L. A., Kozlov P. A., Kolesnikov A. V., Kondratyuk A. A., Kuteinikov V. N. On the issue of iron conversion in the leaching of zinc sulfide materials under atmospheric conditions. Tsvetnye Metally. 2005. No. 5-6. pp. 20–24.
16. Jiang N., Lawson F. Reaction mechanism for the formation of ammonium jarosite. Hydrometallurgy. 2006. Vol. 82, Iss. 3-4. pp. 195–198. DOI: 10.1016/j.hydromet.2006.03.013
17. Geihman V. V., Kazanbaev L. A., Kozlov P. A., Kolesnikov A. V. et al. Study of the effectiveness of flotation in the processing of zinc cakes. Tsvetnye Metally. 2000. No. 5. pp. 32–34.
18. Fattahi A., Rashchi F., Abkhoshk E. Reductive leaching of zinc, cobalt and manganese from zinc plant residue. Hydrometallurgy. 2016. Vol. 161. pp. 185–192. DOI: 10.1016/j.hydromet.2016.02.003
19. Haisheng Han, Wei Sun, Yuehua Hu, Honghu Tang. The application of as a neutralizing agent for the goethite process in zinc hydrometallurgy. Hydrometallurgy. 2014. Vol. 147-148. pp. 120–126. DOI: 10.1016/j.hydromet.2014.05.005
20. Saikova S. V., Panteleeva M. V., Nemkova D. I., Elsufev E. V. Cation exchange resin leaching of zinc from zinc cake and zinc calcine. SibFU Journal. Chemistry. 2022. Vol. 15, No. 4. pp. 580–589. DOI: 10.17516/1998-2836-0320
21. Saikova S. V., Pashkov G. L., Panteleeva M. V. Reactive ion exchange processes of nonferrous metal extraction and dispersion material synthesis. Krasnoyarsk : SibFU, 2018. 198 p.
22. Rodriguez Rodriguez N., Machiels L., Onghena B., Spooren J., Binnemans K. Selective recovery of zinc from goethite residue in the zinc industry using deep-eutectic solvents. RSC Advances. 2020. Vol. 10, Iss. 12. pp. 7328–7335. DOI: 10.1039/D0RA00277A
23. Akhtamov F. E. Heat treatment as a method of processing zinc cakes. International scientific review. 2020. No. 72. pp. 15, 16.
24. Begar A., Djeghlal M. E., Ould Hamou M. Zinc extraction from ghazouat leach residues by using jarosite method. Mining Science. 2021. Vol. 28. pp. 117–126. DOI: 10.37190/msc202809/

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