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Coating Application and Corrosion Protection
ArticleName Comparative analysis of the use of epoxy and fluoroplastic polymer compositions as internal smooth coatings of the inner cavity of steel main gas pipelines
DOI 10.17580/cisisr.2024.02.16
ArticleAuthor E. I. Pryakhin, V. A. Azarov
ArticleAuthorData

Empress Catherine II Saint Petersburg Mining University (St. Petersburg, Russia)

E. I. Pryakhin, Dr. Eng., Prof., Head of the Dept. of Materials Science and Technology of Art Products, e-mail: e.p.mazernbc@yandex.ru
V. A. Azarov, Postgraduate Student, Dept. of Materials Science and Technology of Art Products, e-mail: azarovvolodya@yandex.ru

Abstract

Development of the oil and gas complex is inextricably linked with the improvement of transportation methods for extracted hydrocarbons. Use of internal internal smooth coatings is one of the ways to increase the efficiency of systems transporting natural gas. These coatings allow to reduce the cost of gas transportation and to protect additionally the inner pipe cavity from corrosion damage. Due to the trend of moving natural gas production to areas of the Far North with very low negative temperatures and an increased proportion of heavier hydrocarbon components in the transported gas, it is necessary to propose new technical solutions to ensure the efficient operation of main gas pipelines in new conditions. The authors propose to study the possibility of using a fluoroplastic coating that has not been previously used for gas pipelines and is considered as a promising one. This article presents a comparative analysis of the used epoxy coatings and promising fluoroplastic coatings applied to the surface of steel plates. The epoxy coating was applied to the surface of the plate which was cleaned by sandblasting, and before applying a fluoroplastic coating with low adhesive properties, the plate surface was prepared to ensure a strong adhesive bond by preliminary laser treatment and subsequent cold phosphatizing. In the course of the work, a complex of studies of the physical and mechanical characteristics of coatings was carried out, including determination of the impact strength of coatings at normal and negative temperatures, and determination of elasticity by the Erickson method, as well as determination of bending strength, and determination of equivalent roughness. According to the results of the research, it was revealed that the fluoroplastic coating has greater elasticity, bending strength and impact strength at low temperatures compared to the epoxy coating. In addition, it was found that fluoroplastic coatings are not inferior to epoxy coatings in terms of equivalent roughness, which affects the amount of hydraulic resistance. Thus, this work gives an idea of the relevance of using fluoroplastic coatings as internal smooth coatings to ensure more efficient operation of the gas pipelines in conditions of negative temperatures, with simultaneous increase of the proportion of heavier hydrocarbon components in the transported gas.

keywords Gas pipeline, fluoroplastic coating, epoxy coating, smooth coating, impact strength, coating elasticity, equivalent roughness coefficient
References

1. Skorobogatov V. A., D. Ya. Khabibullin. The role of Senomanian gas in Western Siberia in strengthening and development of Russian gas industry in XX and XXI centuries. Nauchnyi zhurnal Rossiyskogo gazovogo obshchestva. 2021. No. 2 (30). pp. 6–16.
2. Tcvetkov P. S., Fedoseev S. V. Analysis of project organization specifics in small-scale LNG production. Journal of Mining Institute. 2020. Vol. 246. pp. 678–686. DOI: 10.31897/PMI.2020.6.10
3. Litvinenko V. S., Dvoinikov M. V., Trushko V. L. Elaboration of a conceptual solution for the development of the Arctic shelf from seasonally flooded coastal areas. International Journal of Mining Science and Technology. 2022. No. 32 (1). pp. 113–119. DOI: 10.1016/j.ijmst.2021.09.010
4. Gritsenko A. I. Development of the deposits of ethane-containing gases as a key factor in the development of Russian gas industry. Gazokhimiya. 2010. No. 12. pp. 30–33.
5. Laryukhin A. I., Eremina L. N., Mitnitskiy R. A. Monitoring of physical and chemical parameters of hydrocarbons for control and improvement of mining, preparation and transportation of products from Urengoy oil, gas and condensate complex. Nauchno-tekhnicheskiy sbornik Vesti gazovoy nauki. 2013. No. 4 (15). pp. 106–112.
6. Palaev A. G., Krasnikov A. A. Ultrasonic Treatment of Welded Joint from External, Internal and Two Sides on Reduction of Residual Welding Stresses. International Journal of Engineering. 2024. Vol. 37(11). pp. 2171–2180. DOI: 10.5829/ije.2024.37.11b.04
7. Fetisov V. G., Davardoost H. H., Mogylevets V. S. Technological aspects of methane–hydrogen mixture transportation through operating gas pipelines considering industrial and fire safety. Fire. 2023. Vol. 10. Iss. 6. DOI: 10.3390/fire6100409
8. Petkova A. P., Zlotin V. A. Analysis of the efficiency of reducing hydrogen losses in a pipeline made of various austenitic stainless steels. Chernye Metally. 2024. No. 9. pp. 50–54.
9. Luo Y., Liu Y., Zhang D. Y. Advanced progresses in nature gas pipelining applying different drag reduction/energy saving technologies: A review. Eur. J. Environ. Civ. Eng. 2015. Vol. 19. No. 8. pp. 931–949. DOI: 10.1080/19648189.2014.985852
10. Maksarov V. V., Efimova M. V., Filipenko I. A. Choosing parameters of a magnetic abrasive polishing for machining of edges of aircraft body parts from aluminum alloys. Tsvetnye metally. 2024. No. 3. pp. 78–84.

11. Sheshukova E. I., Shibanov D. A., Ivanov S. L., Shishkin P. V. Assessment of loads at the working attachment of a mine shovel (Part 2). Russian Mining Industry. 2024. No. 4. pp. 108–114. DOI: 10.30686/1609-9192-2024-4-108-114
12. Skiba E. D., Shaposhnikov V. V., Kocharyan E. V. Energy saving in the main gas pipeline transport. 2019. Int. Sci. Technol. Conf. “EastConf”, EastConf 2019. 2019. p. 8725183. DOI: 10.1109/EastConf.2019.8725183
13. Taghavi N. Economic investigation on the use of internal coating for natural gas trunk-lines. Chem. Eng. Res. Des. Institution of Chemical Engineers. 2013. Vol. 91. No. 9. pp. 1725–1730. DOI: 10.1016/j.cherd.2013.03.012
14. Zhdaneev O. V. Ensuring the technological sovereignty of the fuel and energy sectors of the Russian Federation. Journal of Mining Institute. 2022. Vol. 258. pp. 1061–1078. DOI: 10.31897/PMI.2022.107
15. Bolobov V. I., Popov G. G. Methodology for testing pipeline steels for resistance to grooving corrosion. Journal of Mining Institute. 2021. Vol. 252. pp. 854–860. DOI: 10.31897/PMI.2021.6.7
16. Popov G. G., Bolobov V. I., Oparina A. O., Shvets A. O. Effect of Hydrogenation on Hardness of Metallic Materials Used in Oil and Gas Industry. International Journal of Engineering, Transactions B: Applications. 2025. Vol. 38 (02). pp. 295–303. DOI: 10.5829/ije.2025.38.02b.04
17. Shaposhnikov N. О., Golubev, I. A., Khorobrov, S. V., Kolotiy A. I., Ioffe A. V., Revyakin V. А. Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2. Journal of Mining Institute. 2022. Vol. 258. pp. 915–923. DOI: 10.31897/PMI.2022.92
18. Yang X. H. et al. Aerodynamic evaluation of an internal epoxy coating in nature gas pipeline. Prog. Org. Coatings. 2005. Vol. 54. No. 1. pp. 73–77. DOI: 10.1016/j.porgcoat.2005.04.001
19. Cui C. et al. Research and Application of Solvent-Free Internal Drag Reducing Epoxy Coating for Non-Corrosive Gas Transmission Service. IOP Conf. Ser. Earth Environ. Sci. 2019. Vol. 252. No. 2. p. 022055. DOI: 10.1088/1755-1315/252/2/022055
20. Shinkin V. N. Springback coefficient of the main pipelines’ steel large-diameter pipes under elastoplastic bending. CIS Iron and Steel Review. 2017. Vol. 14. pp. 28–33.
21. Selivanova N. M. et al. Protecting properties of composite fluoroplastic coatings. Russ. J. Appl. Chem. 2002. Vol. 75. No. 7. pp. 1157–1161. DOI: 10.1023/A:1020736918242
22. Paz-Gomez G. et al. Water-Repellent Fluoropolymer-Based Coatings. Coatings. 2019. Vol. 9. No. 5. p. 293. DOI: 10.3390/coatings9050293
23. Soboleva E. S. et al. Composition and Properties of Aqueous Fluoroplastic Dispersion for Deposition of Metal–Polymer Coatings. Russ. J. Appl. Chem. 2021. Vol. 94. No. 12. pp. 1608–1613. DOI: 10.1134/S1070427221120065
24. Bozhko, G. V. Use of Fluoroplastics in Packing Assemblies of Hydraulic Units. Chemical and Petroleum Engineering. 2001. Vol. 37. No. 9–10. pp. 518–521.
25. Paliivets M. S., Snezhko V. L. Comparative analysis of experimental and theoretical values of Darcy coefficient for determination of experimental wall roughness in metallic polymeric pipeline. Innovatsii i investitsii. 2021. No. 6. pp. 147–150.
26. Zhang K. et al. Influence of laser substrate pretreatment on antiadhesive wear properties of WC/Co-based TiAlN coatings against AISI 316 stainless steel. Int. J. Refract. Met. Hard Mater. 2016. Vol. 57. pp. 101–114. DOI: 10.1016/j.ijrmhm.2016.03.004
27. Studenekin G. et al. Phosphating of Steel in Low-Temperature Solution. Met. 2021 – 30 th Anniv. Int. Conf. Metall. Mater. Conf. Proc. 2021. pp. 748–753. DOI: 10.37904/metal.2021
28. Pryakhin E. I., Azarov V. A. Increasing the adhesion of fluoroplastic coatings to steel surfaces of pipes with a view to their use in gas transmission systems. Chernye Metally. 2024. No. 3. pp. 69–75.
29. Patent No. 2828891 C1 of Russian Federation, MPK B23K 26/00. Pryakhin E. I., Azarov V. A. The method of surface preparation of carbon and low alloy steels for application of polymeric coatings. No. 2024111457. Announced 25.04.2024. Published 21.10.2024. Applicant: Empress Catherine II Saint-Petersburg Mining University.
30. Bouledroua O., Hadj Meliani M., Azari Z. et al. Effect of sandblasting on tensile properties, hardness and fracture resistance of a line pipe steel used in Algeria for oil transport. J. Fail. Anal. and Preven. 2017. Vol. 17. pp. 890–904. DOI: 10.1007/s11668-017-0313-4
31. Vasenin A. B., Stepanov S. E., Zyuzev A. M. et al. Retrospective analysis of the development and prospective of application of pipelines with internal smooth coating. Avtomatizatsiya i IT v neftegazovoy otrasli. 2022. No. 3 (49). pp. 46–56.
32. Vyshemirskiy E. M., Shipilov A. V., Khomenko V. I., Kurochkin A. V. Influence of welding process on internal smooth coating of pipelines and evaluation of allowable width of its removal during pipe mounting for welding. Svarka i diagnostika. 2010. No. 5. pp. 38–41.
33. GOST R 53007-2008. Paint materials. The testing method for quick deformation (impact strength). Introduced: 18.11.2008. Standardinform, 2008. p. 12.
34. GOST 29309-92. Paint coatings. Strength determination for extension. Introduced: 01.01.1993. IPK Izdatelstvo standartov, 1993. p. 7.
35. GOST 31974-2012. Paint materials. The method for coating strength determination during bending around a cylinder rod. Introduced: 01.08.2014. Standardinform, 2014. p. 14.
36. Prodous O. A. Tables for hydraulic calculation of pressure polyethylene pipes: a reference book. St. Petersburg : Izdatelstvo “Dialog”, 2008. 203 p.
37. STO Gazprom 2-2.2-180-2007. Technical regulations for internal smooth coating of pipes for building of main pipelines. Moscow: Izdatelskiy dom “Poligrafiya”, 2008. 12 p.
38. Salnikov S. Yu., Shchurovskiy V. A., Prostokishin V. M. On hydraulic efficiency of main large diameter pipelines. Vesti gazovoy nauki (Scientific and technical collection). 2018. No. 2 (34). pp. 28–35.
39. STO Gazprom 2-3.5-051-2006. Standards of technological engineering for main pipelines. Moscow: Gazprom. 2006. 205 p.

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