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Technological strength properties and workability of materials
ArticleName Analysis of the efficiency of reducing hydrogen losses in a pipeline made of various austenitic stainless steels
DOI 10.17580/chm.2024.09.08
ArticleAuthor A. P. Petkova, V. A. Zlotin
ArticleAuthorData

Empress Catherine II Saint Petersburg Mining University, St. Petersburg, Russia
A. P. Petkova, Dr. Eng., Prof., Dept. of Materials Science and Technology of Art Products, e-mail: apetkova@inbox.ru
V. A. Zlotin, Postgraduate Student, Dept. of Materials Science and Technology of Art Products, e-mail: zlotinvladimir@mail.ru

Abstract

In order to reduce emissions of carbon dioxide into the atmosphere, which is formed as a result of production petroleum products use, it is proposed to use hydrogen as an environmentally friendly energy resource. At the same time, hydrogen has a high permeability through materials, which leads to its inevitable diffusion losses through the pipeline wall during hydrogen transportation and storage. Based on the literature data and mathematical transformations, a computational model was proposed to estimate hydrogen leakage during transportation by a pipeline at a pressure up to 1.2 MPa and at a temperature from 300 to 600 K. Using tabular literature data on permeability coefficients based on the calculation model, possible losses of hydrogen during its transportation through a pipeline made of different grades of austenitic corrosion-resistant steels (304, 304L, 310, 316, 316L, 316LN, 321, 21-6-9, 21-9-9) at temperatures from 300 to 600 K were determined. Based on the results of calculations, it was concluded that 304L steel is the most effective material for reducing hydrogen permeability (maximum losses ~69 l/year at a temperature of 600 K). At the same time, the largest losses of hydrogen are observed in a pipeline made of steel 310 (903 l/year at a temperature of 600 K). In other steels, the volume of losses varies in the range of ~200-300 l/year. The analysis of the steel compositions showed that a decrease in the concentration of carbon, nitrogen, sulfur and phosphorus leads to an increase in its resistance to hydrogen penetration.

keywords Compressed hydrogen, pipeline, permeability, diffusion, losses, austenitic steels, transportation
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