Journals →  Tsvetnye Metally →  2023 →  #9 →  Back

CHRONICLE
ArticleName History behind discovery of rare earth elements. Yttrium
DOI 10.17580/tsm.2023.09.10
ArticleAuthor Detkov P. G., Drobot D. V.
ArticleAuthorData

Solikamsk Magnesium Plant OJSC, Solikamsk, Russia:

P. G. Detkov, Member of the Board of Directors, Candidate of Technical Science, e-mail: p.detkov@yandex.ru

 

Independent Expert, Moscow, Russia:
D. V. Drobot, Doctor of Chemical Sciences, e-mail: dvdrobot@mail.ru

Abstract

The history of rare earth elements can be dated back to 1787 when amateur mineralogist Carl Axel Arrhenius found an unknown heavy black mineral in the Swedish Ytterby. A sample of this mineral was sent for investigation to the University of Abo (currently, Turku) professor Johan Gadolin. During initial studies in 1794, an unknown substance was discovered. Having conducted a quantitative analysis of the material, professor Gadolin found that it had the following composition: silicon oxide – 31%, aluminium oxide – 19%, iron oxide – 12%, unknown oxide, or ‘unknown soil’, – 38%. In 1797, professor Anders Gustaf Ekeberg confirmed Gadolin’s results on the new material and suggested that the new oxide bear a Latin name – Yttria and the mineral should be called ytterbite, referring to the area where it had been discovered. In 1800, the mineral was studied by German chemist Martin Heinrich Klaproth, who also confirmed the fact of discovering a new compound and establishe dthat the mineral contained beryllium oxide instead of aluminium oxide, as was believed by Gadolin and Ekeberg. Klaproth suggested renaming the mineral ‘gadolinite’ in honour of the person who had first discovered the new compound. Later on, as the chemical analysis techniques developed further, other rare earth elements were distinguished in gadolinite, including terbium, ytterbium and erbium. Their names relate to the Swedish village where the new mineral was first discovered.

keywords Rare earth clement, mineral, discovery, analysis, Johan Gadolin, yttrium, gadolinite
References

1. Vom Hrn Bergm. Geijer in Stockholm. Chemische Annalen für die Freunde der Naturlehre, Arzneygelahrtheit, Haushaltungskunst und Manufakturen. 1788. Vol. 1. pp. 229, 230.
2. Gadolin J. Undersokning af en svart tung Stenart ifran Ytterby Stenbrott in Roslagen. Kongl. Vetenskaps Academiens niy Handingar. 1794. Vol. 15. pp. 137–155.
3. Gadolin J. Von einer schwarzen schweren Steinart aus Ytterby Steinbruch in Roslagen in Schweden. Chemische Annalen für die Freunde der Naturlehre, Arzneygelahrtheit, Haushaltungskunst und Manufakturen. 1796. Vol. 1. pp. 313–329.
4. Ekeberg A. G. Ytterligare undersokningar at den svarta Stenarten fran Ytterby och den dari funda egna jord. Kongl. Vetenskaps Academiens niy Handingar. 1797. Vol. 18. pp. 156–164.
5. Klaproth M. H. Untersuchung des Gadolinits. Sammlung der deutschen Abhandlungen, welche in der Königlichen Akademie der Wissenschaften zu Berlin vorgelesen worden in den Jahren 1798–1800. Vol. 1803. pp. 58–70.
6. Klaproth M. H. Einige Bemerkungen uber den Gadolinit, den Chryolith und die Honigsteinsäure. Chemische Annalen für die Freunde der Naturlehre, Arzneygelahrtheit, Haushaltungskunst und Manufakturen. 1801. Vol. 1. pp. 307, 308.
7. Mikhaylichenko A. I., Mikhlin E. B., Patrikeev Yu. B. Rare earth metals. Moscow : Metallurgiya, 1987. 232 p.
8. Korovin S. S., Zimina G. V., Reznik A. M. Rare and trace elements. Chemistry and technology: In 3 volumes. Vol. 1: Textbook for university students. Ed. by S. S. Korovin. Moscow : MISiS, 1996. 376 p.
9. Polyakov E. G., Nechaev A. V., Smirnov A. V. Metallurgy of rare earth metals. Moscow : Metallurgizdat, 2018. 732 p.
10. Balaram V. Rare earth elements: A review of application, occurrence, exploration, analysis, recycling and environmental impact. Geoscience Frontiers. 2019. No. 10, Iss. 4. pp. 1285–1303.
11. Johrendt D. Rare earth based superconducting materials. Rare Earth Chemistry. Berlin : De Gruyter, 2020. pp. 557–575.
12. Binnemans K., Jones P. T., Müller T., Yurramendi L. Rare Earths and the Balance Problem: How to Deal with Changing Markets? Journal of Sustainable Metallurgy. 2018. Vol. 4. pp. 126–146.
13. Wentker M., Jüstel T., Leker J. Economical aspects. Rare Earth Chemistry. Berlin : De Gruyter, 2020. pp. 611–627.

Language of full-text russian
Full content Buy
Back