Ecology and Recycling |
ArticleName |
Ferrum extraction in cast iron via reduction smelting of red mud |
DOI |
10.17580/cisisr.2023.01.19 |
ArticleAuthor |
N. V. Vasyunina, I. V. Dubova, K. E. Druzhinin, T. R. Gilmanshina |
ArticleAuthorData |
Siberian Federal University (Krasnoyarsk, Russia):
N. V. Vasyunina, Cand. Eng., Associate Prof. I. V. Dubova, Cand. Eng., Associate Prof.
T. R. Gilmanshina, Cand. Eng., Associate Prof., Head of the Dept. of Technosphere Safety of Mining and Metallurgical Production, e-mail: gtr1977@mail.ru
Elkor JSK (Krasnoyarsk, Russia): K. E. Druzhinin, Director
Cand. Eng., Associate Prof. A. A. Kovaleva participated in this research. |
Abstract |
High-iron Bayer red mud, including more than 30 % Fe, is considered as poor iron ore. Owing to global iron deficiency during last decades, the problem of efficient use of iron which is containing in red mud with high Fe content attracts most and most attention. This research includes development of the technological route for Fe extraction from red mud in cast iron via reduction smelting with consequent accelerated cooling for metal separation from slag. Influence of different experimental parameters (such as temperature, basicity and reduction time) on Fe extraction from red mud was examined in details. The results displayed that separation between metal and slag was complete. Maximal Fe extraction in cast iron was obtained at the temperature 1450 °С and made in average 88.5 % (when using fluxes without soda) and 91.5 % (with soda addition). Microstructure of the samples was determined, it showed the structure of hyper-eutectic white cast iron (ledeburite + graphite). No non-metallic inclusions were revealed in the structure of samples. Optimal experimental results are very important for achievement of large-scale and highefficient red mud recovery. |
keywords |
Red mud, cast iron, reduction smelting, ferrum, recycling, alumina production wastes, red mud
processing, technological route of recycling |
References |
1. Wang Y. X. et al. Recovery of alkali and alumina from bauxite residue (red mud) and complete reuse of the treated residue. Journal of Cleaner Production. 2018. Vol. 188. pp. 456–465. 2. Zinoveev D. V. Et al. Review of global practice of red mud processing. Part 1. Pyrometallurgical methods. Izvestiya vysshikh uchebnykh zavedeniy. Chernaya metallurgiya. 2018. Vol. 61. No. 11. pp. 843-858. 3. Liu X. et al. Characteristic, hazard and iron recovery technology of red mud - A critical review. Journal of Hazardous Materials. 2021. Vol. 420. pp. 126542. 4. Araújo P. F. M. et al. Bayer process towards the circular economy – Metal recovery from bauxite residue. Light Metals 2020. Springer, Cham, 2020. pp. 98–106. 5. Borra C. R. et al. Leaching of rare earths from bauxite residue (red mud). Mineral Engineering. 2015. Vol. 76. pp. 20–27. 6. Chesnikov Yu. A. et al. Pyrometallurgical processing of wastes of aluminium production. Vestnik Magnitogorskogo gosudarstvennogo tekhnicheskogo universiteta im. G. I. Nosova. 2013. No. 3 (43). pp. 19-22. 7. Agrawal S., Dhawan N. Evaluation of red mud as a polymetallic source – A review. Minerals Engineering. 2021. Vol. 171. pp. 107084. 8. Chao X. et al. Effect of Concentrations and Pressures of CO2 on Calcification – Carbonation Treatment of Bauxite Residue. Light Metals 2020. 2020. pp. 124–128. 9. Zinoveev D., Grudinsky P., Zakunov A., Semenov A., Panova M., Valeev D., Kondratiev A., Dyubanov V., Petelin A. Influence of Na2CO3 and K2CO3 Addition on Iron Grain Growth during Carbothermic Reduction of Red Mud. Metals. 2019. No. 9. 1313. DOI: 10.3390/met9121313 10. Liu Y. J. et al. Recovery of Ferric Oxide from Bayer Red Mud by Reduction Roasting-Magnetic Separation Process. Journal of Wuhan University of Technology. 2016. Vol. 31. pp. 404–407. 11. Guo Y. H. et al. Nuggets Production by Direct Reduction of High Iron Red Mud. Journal of Iron and Steel Research, International. 2013. Vol. 20. pp. 24–27. 12. Rao M. J. et al. Iron Recovery from Red Mud by Reduction Roasting-Magnetic Separation. Light metals. 2013. pp. 125–130. 13. Wang K. et al. Recovery of Iron from High-Iron Bayer Red Mud by Smelting Reduction. Light Metals. 2020. pp. 92–97. 14. Vasyunina N. V., Dubova I. V., Gilmanshina T. R. et al. Extraction methods for valuable elements (Fe, Al, Na, Ti) from red mud. Ekologiya i promyshlennost Rossii. 2020. Vol. 24. No. 9. pp. 32–38. 15. Li X. B. et al. Recovery of alumina and ferric oxide from Bayer red mud rich in iron by reduction sintering. Transactions of nonferrous metals society of China. 2009. Vol. 19 (5). pp. 1342–1347. 16. Romanova O. A., Sirotin D. V. Methods of determination of ecological and economical efficiency in processing of Ural mancaused formations. Ekonomika regiona. 2021. Vol. 17. Iss. 1. pp. 59-71. DOI: 10.17059/ekon.reg.2021-1-5 17. Khanna R. et al. Red Mud as a Secondary Resource of Low-Grade Iron: A Global Perspective. Sustainability. 2022. Vol. 14. No. 3. p. 1258. 18. Balomenos E. et al. A Novel Red Mud Treatment Process: Process design and preliminary results. Mineral Processing & Extractive Metallurgy. 2011. Vol. 32. pp. 1–21. |
Full content |
Ferrum extraction in cast iron via reduction smelting of red mud |