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SCIENTIFIC DEVELOPMENTS OF THE NATIONAL RESEARCH TOMSK STATE UNIVERSITY IN THE FIELD OF SCIENCE AND TECHNOLOGY OF RARE AND RARE EARTH METALS AND MATERIALS ON THEIR BASE
ArticleName Zinc Compounds Obtained from the Karatau Phosphorites and Removal of Paraffins from Petroleum Products Using Synthesized Carbon Nanosorbents Containing Zinc
DOI 10.17580/tsm.2022.03.04
ArticleAuthor Ryspanov N. B., Sadieva Kh. R., Alpysbaeva Zh. T., Kozhamzharova L. S.
ArticleAuthorData

National Academy of Mining, Nur-Sultan, Republic of Kazakhstan:

N. B. Ryspanov, President, Doctor of Technical Sciences, e-mail: nbr21@mail.ru

Zh. T. Alpysbaeva, Chief Academic Secretary, Candidate of Biological Sciences, e-mail: jannat69@mail.ru

 

M. Kh. Dulati Taraz Regional University, Taraz, Republic of Kazakhstan:
Kh. R. Sadieva, Associate Professor, Candidate of Technical Sciences, e-mail: xalipa71@mail.ru

 

Yessenov University, Aktau, Republic of Kazakhstan:
L. S. Kozhamzharova, Professor, Candidate of Biological Sciences, e-mail: erasl2006@mail.ru

Abstract

This paper describes an environmentally friendly and low-waste process that helps produce zinc-containing nanosorbents by processing phosphorite material. Compositional analysis of phosphorites showed that the impurities and magnesium contained in the Karatau ores (the latter is found in the form of dolomite) could make the direct processing of these ores much more complicated. A new safe and cost-effective technique has been developed for extraction of transition and rare elements. The samples obtained were studied on an Agilent 4200 MP-AES unit using atomic emission spectroscopy. The paperalso desc ribes a technique that uses recovered rare earth and transition elements to make nanocatalysts. These studies are of great scientific and practical interest as more research is necessary to better understand the adsorption of zinc ions on the nanosorbent surface. Chromatographic analysis of the obtained samples was carried out on a Perkin-Elmer AutoSystem LX gas chromatograph. The CN-CVD-100 method and a carbon nanotube were used for the absorption of free carbon atoms on the surface of the recovered compounds. The synthesized reagents are finely dispersed nanosorbents with a self-expressed structure. Studies have been carried out that looked at using the synthesized samples to reduce the paraffin content in petroleum products. The percent concentration of paraffins in oil was analyzed on a gas chromatograph. It was found that nanosorbents do have an effect on the oil composition as nanoparticles tend to quickly absorb impurities contained in the water and thus actively interact when the surface layers come into contact. With the help of experiments, it is shown that the zinc-containing nanosorbent synthesized following the proposed technique can be used for treatment of liquid chemical and petrochemical waste and wastewater. The use of zinc-containing nanosorbents as a special class of nanoparticles is a rather promising area.
Contributors to this research work include E. Atenov, a doctoral student at the M. Kh. Dulati Taraz Regional University in Taraz, Republic of Kazakhstan.

keywords Karatau phosphorites, ground phosphate rock, Koksu deposit, zinc sorbents, nanosorbent, carbon nanotube, zinc-containing carbon nanosorbents, nanoparticles
References

1. Urbanczyk L., Milde D., Figura M., Cholewa J. et al. Possibilities of obtaining high quality solid phosphorus pentoxide from white phosphorus of Kazakh origin. Przemysl Chemiczny. 2018. Vol. 97, No. 4. pp. 557–559.
2. U. S. Geological Survey. Mineral Commodity Summaries. U. S. Geological Survey: Reston, VA, USA. 2018. pp. 122, 123.
3. Ruan Y., Zhang Z., Luo H., Xiao C. et al. Effects of metal ions on the flotation of apatite, dolomite and quartz. Minerals. 2018. Vol. 8, Iss. 4. p. 141.
4. Alimov U. K., Rasulov A. A. et al. Optimal regime of Central Kyzylkum phosphorite processing by evaporated wet process phosphoric acid. Universum. 2016. No. 8. pp. 26–32.
5. Kudaybergenova N. K., Stetsyura M. M., Fazylova O. S., Semashko V. A. The copper-bearing mineral of cuprite in Kazakhstan deposits. Bulletin of the National Academy of Sciences of the Republic of Kazakhstan. 2017. Vol. 2, No. 422. pp. 31–36.
6. Masalimova B. K., Sadieva Kh. R., Matniyazova G. K., Tsoy I. G. et al. Extracting rare earth elements from Karatau phosphorites. Bulletin of the National Academy of Sciences of the Republic of Kazakhstan. Series: Geology and Engineering. 2018. No. 3. pp. 309–316.
7. Yabe Т., Suzuki Y., Saloh Y. Renewable energy cycle with magnesium and solar-energy-pumped lasers. Renewable Energy and Power Quality Journal. 2014. Vol. 1, No. 12. Paper 236.
8. Sadieva Kh. R., Nauryzbekov Zh. K. A study of zinc-bearing nanosorbents extracted from phosphoritic ore. Global science and innovations 2020: Central Asia. 29 February, 2020 in Nur-Sultan (Astana), Kazakhstan. pp. 62–66.
9. Sadieva Kh. R., Baltabaeva D. G., Eleuken A., Tolegen N. et al. Decomposition of Karatau phosphorites with mineral acids and recovery of rare earth elements from secondary concentrates. Innovative Development and Popularity of Science in Today’s Kazakhstan: 11th International Science Conference. 2017. pp. 55–59.
10. Mahendiran D., Subash G., Selvan D. A., Rehana D. et al. Biosynthesis of zinc oxide nanoparticles using plant extracts of Aloe vera and Hibiscus sabdariffa: Phytochemical, antibacterial, antioxidant and antiproliferative studies. Bionanoscience. 2017. pp. 530–545.
11. de Oliveira Primo J., Bittencourt C., Acosta S., Sierra-Castillo A. et al. Synthesis of zinc oxide nanoparticles by ecofriendly routes: adsorbent for copper removal from wastewater. Frontiers in Chemistry. 2020. 27 November. DOI: 10.3389/fchem.2020.571790.
12. Patil B. N., Taranath T. Limonia acidissima L. leaf mediated synthesis of silver and zinc oxide nanoparticles and their antibacterial activities. Microbial Pathogenesis. 2018. Vol. 115. pp. 227–232.

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