ArticleName |
Obtaining of ferrosilicochromium powder alloy by silicothermic reduction and study of the mechanism of this process |
ArticleAuthorData |
National Polytechnic University of Armenia (Erevan, Armenia):
V. H. Martirosyan, Dr. Eng., Prof., Dept. of General Chemistry and Chemical Processes, E-mail: v.a.martorosyan@mail.ru M. E. Sasuntsyan, Cand. Eng., Associate Prof., Dept. of General Chemistry and Chemical Processes, E-mail: msasuntsyan@mail.ru
Institute of Powder Metallurgy (Minsk, Belarus):
V. V. Savich, Cand. Eng., Associate Prof., 1st Deputy General Director, E-mail: savich.vadim@gmail.com |
Abstract |
The process of obtaining a powder ferrosilicochromic alloy by the method of silicothermic reduction of local chromites and slags of copper smelters was investigated. The mechanism of this process has been studied. It is established that the best results are obtained in the case of slag / chromite ratio = 1:1, when an alloy with microdispersed structure and high strength is obtained. The optimum composition of the resulting alloy is as follows: 35.1% Fe; 36,35% Si and 28.53% Cr, with a metal yield of 98.4%. The obtained alloy powder can be used as an acidified and alloying additive to chromium- and siliconcontaining stainless composite materials. The aspects of the process for obtaining FeSiCr alloy have been developed. The maximum temperature (Tc) and the linear propagation velocity of the combustion wave (Uv) are determined graphically. The mechanism of the formation of FeSiCr in the SHS process is explained.
This work was financially supported by the RA MES State Committee of Science and Belarusian Republican Foundation for Fundamental Research (RB) within the framework of the joint research projects SCS and BRFFR — accordingly (13-РБ049 and AБ16/48). |
References |
1. Sasuntsyan M. E. Chromium obtaining from Armenian chromite concentrates by SHS. National science review of Oxford University Press. 2017. No. 4(2). pp. 1315–1326. 2. Puchkov L. A., Vorobiev A. G., Fedina O. V. “Gornyi Zhurnal” and development of mining in Russia. Gornyi zhurnal. 2015. No. 7. pp. 5–12. 3. Motovilov I. Y., Luganov V. A., Mishra B., Chepushtanova T. A. Oxide powders production from iron chloride. CIS Iron and Steel Review. 2018. Vol. 15. pp. 28–32. 4. Pliner J. L., Ignatenko G. F., Lappo C. I. Chromium Metallurgy. M.: Metallurgiya. 2012. 362 p. 5. Smelov V. G., Sotov A. V., Agapovichev A. V. Study of structures and mechanical properties of products manufactured via selective laser sintering of 316L steel powder. Chernye metally. 2016. No. 9. pp. 61–65. 6. Aloyan P. G. Material composition and metalliferous of chromite ores of Tapasar deposit. Erevan : JSC “Mining — Metallurgical Institute of Sevan ophiolitic stripes”. 2005. 32 p. 7. Martirosyan V. A., Sasuntsyan M. E., Savich V. V. Obtaining a superconcentrate and powdery chromium from chromite ore. Metallurg. 2018. No. 4. pp. 54–58. 8. Tripathy S. K., Banerjee P. K., Suresh N. Magnetic separation studies on ferruginous chromite fine to enhance Cr : Fe ratio. International Journal of Minerals, Metallurgy, and Materials. 2015. Vol. 22. Iss. 3. pp. 217–224. DOI: 10.1007/s12613-015-1064-4. 9. Akar Sen G. Application of full factorial experimental design and response surface methodology for chromite benefication by Knelson concentrator. Minerals. 2016. Vol. 6. Iss. 1. p. 5. DOI: 10.3390/min6010005. 10. Gladishev S. V., Abdulvaliev R. A., Kenzhaliev B. K. et al. Obtaining the chromite concentrate from enrichment tailings. Complex usage of mineral raw materials. 2018. No. 1. pp. 12–17. 11. Bhambhani T., Nagaraj D. R., Yavuzran O. Improving flotation recovery of oxide copper minerals. IMPC XXVIII Congress. 2016. pp. 1–13. 12. Ibraev I. I., Ibraeva O. T., Suyundikov M. M. Disposal of chromium-containing slurries. Metallurg. 2012. No. 10. pp. 28–30. 13. Leontyev L. I., Sheshunov O. Yu., Nekrasov I. V. Analysis, processing and use of industrial wastes of metallurgical production. Complex usage of mineral raw materials. 2014. No. 4. pp. 8–25. 14. Martirosyan V. A., Sasuntsyan M. E. The study of metallurgical slags of metallurgical plants of Armenia during the fine grinding. Bulletin of HEI. Ferrous Metallurgy. 2019. Vol. 62. No. 1. pp. 8–14. DOI: 10.17073/0368-0797-2019-1-8-14. 15. Sasuntsyan M. E. High-temperature synthesis of the iron monosilicide from production slags. Proc. RA NAS and SEUA. Ser. ТН. 2018. Vol. 71. No. 1. pp. 3–9. 16. Martirosyan V., Torosyan G., Sasuntsyan M., Torosyan N. Chromium obtaining from Armenian chromite concentrate by SHS in the presence of chloride. Meridian ingineresc. 2012. No. 2. pp. 33–37. 17. Martirosyan V. A., Sasuntsyan M. E. Investigating the structurization process of iron monosilicide powders obtainig by High-Temperature Sintesis from the preliminarily mechanoactivated burden. JSEMAT. 2016. Vol. 6. No. 2. pp. 47–57. DOI: 10.4236/jsemat.2016.62005.1713. 18. Martirosyan V., Sasuntsyan M. Complex mineralogical investigation of copper and molybdenum slags in the acting metallurgical plants of Armenia. Yale Journal of Science and Education. 2016. No. 10. pp. 413–420. 19. Sokolov I. P., Chekmarev A. M., Seleznev V. P., Kozyrev A. V. Peculiarities of solid-state metallothermic reactions. Izvestiya RAN “Metally”. 1990. No. 2. pp. 15-17. 20. Senchenko A. E., Kulikov Yu. V., Kurchevskaya E. M. Investigation of the material composition of Udokan copper deposit ores using the modern methods of process mineralogy. Tsvetnye metally. 2017. No. 10. pp. 25–35. DOI: 10.17580/tsm.2017.10.03. 21. Philipova N. A. Phase analysis of ores and products of their processing. M.: Izdatelstvo “Khimiya”. 1975. 280 p. 22. Revenko A. G. X-ray spectral fluorescence analysis of natural materials. Novosibirsk: Izdatelstvo “Nauka”. 1994. 264 p. 23. Mazalov L. N. X-ray spectra and chemical relation. Novosibirsk: Izdatelstvo “Nauka”. 1982. 111 p. 24. Pichugin V. F., Yanovskiy V. P., Morosova N. S., Yermolovich I. M. Proceedings of 10th International Conference on Modification of materials with Particle Beams and Plasma Flows. Tomsk. 2010. pp. 672 -675. 25. Zenin A. A., Nersisyan G. A. Mathematical theory of combustion and explosion. M.: Izdatelstvo “Nauka”. 1980. 478 p. 26. Zenin A. A., Nersisyan G. A. Study of the structure of the heat wave in SHS processes by the example of boride synthesis: Preprint. Chernogolovka: IOCHF. 1980. 28 p. 27. Zenin A. A., Nersisyan G. A. Thermal structure of the SHS wave, mechanisms and macrokinetics of High-temperature interaction of elements in the system Ti–Si and Zn–Si. Preprint. Chernogolovka: IOCHF. 1980. 42 p. |