Название |
Flotation activity of pyrite in the separation of massive sulphide ores |
Информация об авторе |
Moscow University of Science and Technology “MISiS”, Moscow, Russia: V. A. Ignatkina, Professor of the Department of Mineral Processing, e-mail: woda@mail.ru V. A. Bocharov, Professor of the Department of Mineral Processing A. A. Kayumov, Post-Graduate Student of the Department of Mineral Processing, e-mail: maliaby_92@mail.ru M. Aksenova, Masters's graduate of the Department of Mineral Processing |
Реферат |
Pyrite is the main mineral of pyrite copper ores that due to the high initial content in ore (in comparison with sulfides of non-ferrous metals and rock minerals) and technological features affects in mineral separation efficiency of non-ferrous and noble metals. Technological properties of pyrite depend on its texture-structural varieties; content of admixtures (copper, gold, zinc, plumbum); size; type of inclusion; bonding with other sulfides; compound of isomorphic admixtures of rare-earth minerals (thallium, gallium, selenium, cobalt, germanium). The relations between pyrite’s flotation activity and pH (7; 9; 11) at presence of modifiers (sodium sulfite, zinc sulfate, sulfite and sodium bisulfide, sodium cyanide) which, with the exception of zinc sulphate at a concentration of more than 5·10–3 g-eq/l, is depressed in a lime environment (at pH > 11) pyrite flotation. The deep depression of pyrite requires much less amount of sodium cyanide than sodium sulfide. Pyrite’s flotation activity from mixture (chalcopyrite and sphalerite) is higher than monomineral fraction. The type of sulfhydryl collector (butyl xanthate, diisobutyl dithiophosphate, isopropyl-O-N-methylthionocarbamate (ITС), Aero 5100, M-TF) with aeration differently affects in pyrite’s flotation activity. It leads to an increased specific flotation rate of pyrite by thionocarbamates in some aeration conditions. This work was carried out with the financial support of the Russian Foundation for Basic Research, project No. 17-05-00890. |
Библиографический список |
1. Bocharov V. A., Ignatkina V. A., Khachatryan L. S., Makavetskas A. R., Bondarev A. A. Technology of selective flotation of pyrite copper-zinc ores. Gornyi Zhurnal. 2012. No. 6. pp. 70–74. 2. Ozhogina E. G., Gorbatova E. A., Gazaleeva G. I. Technology of concentration of copper and copper-zinc ores in the Urals. Ed.: V. A. Chanturiya, I. V. Shadrunova. Moscow : Nauka, 2016. 386 p. 3. Bocharov V. A., Ignatkina V. A. Mineral concentration technology. Moscow : “Ore and Metals” Publishing House, 2007. Part 1. 472 p. 4. Kislyakov L. D., Kozlov G. V., Bocharov V. A. Flotation of copper and copperzinc ores of the Urals. Moscow : Nedra, 1966. 387 p. 5. Bocharov V. A., Ignatkina V. A. The analysis of modern directions for all-round utilization of base metals refractory ores. Obogashchenie Rud. 2015. No. 5. pp. 46–53. DOI: 10.17580/or.2015.05.08 6. Chanturiya E. L., Bortnikov N. E., Kripov O. I. Interaction of internal aeging, chemical composition and technological properties of pyrite. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh. 2005. No. 3. pp. 90–98.
7. Ignatkina V. A., Bocharov V. A. Complex mastering of pyrite gold-bearing ores of non-ferrous metals. Tsvetnye Metally. 2007. No. 8. pp. 18–28. 8. Izoitko V. M. Technological mineralogy and ore assessment. Moscow : Nedra, 1997. 581 p. 9. Eliseev N. I., Kirbitova N. V., Panova N. I. Influence of genetic peculiarities of pyrite on distribution of collector in flotation system. Izvestiya vuzov. Tsvetnaya metallurgiya. 1992. No. 5/6. pp. 15–19. 10. Chanturiya E. L. Mineralogical and technological types of pyrite in Gai deposit. Gornyy informatsionno-analiticheskiy byulleten. 2005. No. 12. pp. 263–273. 11. Yianatos J., Carrasco C., Vinnett L., Rojas I. Pyrite recovery mechanisms in rougher flotation circuits. Minerals Engineering. Vol. 66–68. November 2014. pp. 197–201. 12. Mermillod-Blondin R., Kongolo M., de Donato R. Pyrite flotation with xantate under alkaline conditions – application to environmental desulfurization. Century of flotation symposium, Brisbane, QLD, 6–9 June 2005. pp. 683–692. 13. Bocharov V. A., Sapozhnikov V. P. Protective role of modifiers in iron oxidation reaction during the sulfide ore grinding. Fiziko-tekhnicheskie problemy razrabotki poleznykh iskopaemykh. 1977. No. 1. pp. 66–69. 14. Abramov A. A. Non-ferrous metal ore concentration technology. Moscow : Nedra, 1983. 358 p. 15. Bocharov V. A., Ignatkina V. A. On role of iron and its compounds in processes of enrichment of nonferrous and precious metal sulfide ores. Izvestiya vuzov. Tsvetnaya metallurgiya. 2007. No. 5. pp. 4–12. 16. Mitrofanov S. I. Selective flotation. Moscow : Nedra, 1968. 583 p. 17. Kakovskiy I. A. Flotation modifiers. Physical and chemical basis of flotation theory. Moscow : Nauka, 1983. Chapter 4. pp. 189–201. 18. Goryachev B. E., Naing Linoo, Nikolaev A. A. Peculiarities of flotation of pyrite of one of copper-zinc deposits of Ural region by potassium butyl xanthate and sodium dithiophosphate. Tsvetnye Metally. 2014. No. 6. pp. 18– 22. 19. Abramov A. A. Flotation. Physical and chemical modeling of processes. Moscow : Gornaya kniga, 2010. 606 p. 20. Yufan Mu, Yongjun Peng, Rolf A. Lauten. The depression of pyrite in selective flotation by different reagent systems – A Literature review. Minerals Engineering. Vol. 96–97. October 2016. pp. 143–156. 21. Bao Guo, Yongjun Peng, Gretel Parker Electrochemical and spectroscopic studies of pyrite–cyanide interactions in relation to the depression of pyrite flotation. Minerals Engineering. June 2016. Vol. 92. pp. 78–85. 22. Bocharov V. A., Ignatkina V. A., Kayumov A. A. Methods of gold recovery during the concentration of refractory gold-bearing pyritic copper-zinc ores. Part 2. Technological peculiarities of gold associations release from pyritic copper-zinc ores. Tsvetnye Metally. 2017. No. 5. pp. 13–20. DOI: 10.17580/tsm.2017.05.02. 23. Xumeng Chen, Yongjun Peng, Dee Bradshaw. Effect of regrinding conditions on pyrite flotation in the presence of copper ions. International Journal of Mineral Processing. Vol. 125, 10 December 2013. pp. 129–136. 24. Bocharov V. A. Mechanism of oxidation of pyrite and peculiarities of flotation of sulfide minerals of copper-zinc ores. Theory of the processes of production of heavy non-ferrous metals. Collection of scientific proceedings. Moscow : Gintsvetmet, 1989. pp. 160–165. |