ArticleName |
Mineral genesis and paragenesis energy aspects |
Abstract |
Based on the atom kernels and binding electrons crystal chemistry, developed by the author, rocks and ores formation processes energy analysis was performed, explaining the nature of associated occurrence of minerals in paragenetic associations and intergrowths. Forthis purpose, minerals’ energy parameters EV, kJ/cm3, (energy density) and WV, MJ/cm3, (energy-to-volume ratio of atom kernels and binding electrons) are applied. Closeness of respective minerals’ energy parameters in paragenetic associations is indicative of closely time-spaced events of their formation, as well as order (sequence) of minerals’ segregation. The criteria of deep-seated (hypogene) and surficial (supergene) genesis of minerals and their associations were revealed, providing numerous examples. Secondary hypogene minerals’ energy parameters increase regularity was established in comparison with subjacent earlier segregated primary supergene minerals, possessing, as a rule, lower energy parameters. The problem of minerals’ associations formation in ores, considered in detail, may be directly relevant to beneficiation, providing for metallurgists a possibility of focused scientific approach to detection and identification of valuable and associated minerals in ores, with that, the latter also may be involved in ore enrichment. |
References |
1. Fersman A. E. Selected works. Vol. IV. Moscow: Publ. AN SSSR, 1958. 588 p. 2. Urusov V. S. Energy crystal chemistry. Мoscow: Nauka, 1975. 335 p. 3. Godovikov A. A. Mineralogy. Moscow: Nedra, 1983. 647 p. 4. Mamyrov E. M. Differentiation of the most common lithosphere substances on the atomization specific energy. Frunze: Ilim, 1989. 163 p. 5. Evzikova N. Z. On the distribution of minerals on the ore sphere energy levels. Mineralogy — the basis of the use of complex ores. Abstracts of the Annual Meeting of the Russian Mineralogical Society. St. Petersburg, 2001. pp. 12–15. 6. Zuyev V. V. Energy density, properties of minerals and the energy structure of the Earth. St. Petersburg: Nauka, 1995. 128 p. 7. Zuyev V. V. Spanning-electron crystal chemistry and properties of minerals (with the use of Fersman additive geoenergy concept). Lambert Academic Publishing, 2012. 324 p. 8. Korinevsky V. G. The rare case of myrmekite intergrowths of ilmenite and fassaite. Zapiski RMO. 2007. Pt. 136, Iss. 2. pp. 56–62. 9. Ramdohr P. Die Erzmineralien und ihre Verwachsungen. 3rd ed. Berlin: Akademie Verlag, 1960. 1089 p. 10. Suzuki M., Tagai T., Hoshi T., Takeda H. Oriented growth of chlorite and zoisite in plagioclase as alteration products — examples of graphoepitaxy. Mineralogical Journal. 1994. Vol. 17, No. 4. pp. 181–188. 11. Logvinenko N. V., Gramberg I. S. Introduction to geochemistry of exogenous processes. St. Petersburg: Publ. Sankt-Peterburgskiy Gosudarstvennyy Universitet, 1997. 132 p. 12. Velbel M. A. Formation of protective surface layers during silicate-mineral weathering under well-leached, oxidizing conditions. American Mineralogist. 1993. Vol. 78, No. 3–4. pp. 405–414. 13. Tkachev A. V., Sergeeva N. E. Assotiations of sulphides and conditions of their origin in pegmatites of muscovite formation. Zapiski VMO. 1994. Pt. 123, Iss. 4. pp. 21–30. 14. Besedin E. V. An ontogenetic notice on the granular garnet-magnetite aggregate from the Dashkesan iron ore deposit. Zapiski VMO. 1972. Pt. 101, Iss. 6. pp. 444–445. 15. Pogrebs N. A. Mineralogy and genesis of ore formations of Pravourmiyskoye tin ore deposit. Author’s abstract of candidate of geological and mineralogical sciences dissertation. St. Petersburg, Sankt-Peterburgskiy Gosudarstvennyy Gornyy Institut, 1993. 37 p. 16. Bulakh A. G. Mineralogy with the basics of crystallography. Moscow: Nedra, 1989. 351 p. 17. Zuyev V. V. Introduction to energy geochemistry. Lambert Academic Publishing, 2014. 163 p. 18. Ostrovskiy I. A. Fluorapatite isobaric potential at high parameters and antagonism of apatite and diamond. Geokhimiya. 1994. No. 10. pp. 1520–1524. 19. Kostov I., Mincheva-Stefanova I. Sulfide minerals. Moscow: Mir, 1984. 281 p. 20. Fillie S. Genesis and paragenesis of the tetravalent Mn ores and Mn-Fe ores in secondary banded iron formations from Nigeria. Proceeding of the 3rd World Conference on Applied Science, Engineering and Technology. September 27–29, 2014. Kathmandu, Nepal. pp. 318–328. 21. Advanced mineralogy. Vol. 1. Composition, structure, and properties of mineral matter: Concepts, results, and problems. Ed. Marfunin A. S. Berlin: Springer-Verlag, 1994. 550 p. |