Journals →  Non-ferrous Metals →  2016 →  #1 →  Back

METAL PROCESSING
ArticleName Titaniferous protective coatings on aluminum alloys
DOI 10.17580/nfm.2016.01.06
ArticleAuthor Abrashov A. A., Grigoryan N. S., Vagramyan T. A., Zhilenko D. Yu.
ArticleAuthorData

Dmitry Mendeleev University of Chemical Technology of Russia, Moscow, Russia:

A. A. Abrashov, Assistant Professor, Department of Innovation materials and corrosion protection, e-mail: abr-aleksey@yandex.ru
N. S. Grigoryan, Assistant Professor, Department of Innovation materials and corrosion protection
T. A. Vagramyan, Professor, Head of Department of Innovation materials and corrosion protection
D. Yu. Zhilenko, Student, Department of Innovation materials and corrosion protection

Abstract

Recent trends in world practice are toward more often use of nanoscale adhesive coating obtained from hexafluorotitanit acid solutions as an alternative to chromate layers on aluminum and aluminum alloys. The present article is devoted to the development of technology of obtaining such coatings. There was worked out a process of titaniferous coatings depositing on aluminum and AMg6 (АМг6) and AK12 (АК12) alloys, which are comparable with chromate coatings by corrosion stability and defense capability and may serve as an alternative of the latters. The solution comprises, g/l: H2TiF6 — 1–2; Mn2+ — 0.06–0.12; tartaric (citric) acid — 0.3–0.4; (NH4)2MoO4 —1–3. It was found that permissible PH values of solution lie in the range of 4.5–5.0 units. It has been revealed that introducing 0.3–0.4 g/l of tartaric or citric acid into operating solution not only stabilizes рН value of the solution, but also brings to the growth of defense capability of the generated coatings. Chemical composition of coatings has been determined by methods of X-ray photoelectron spectroscopy. It has been assumed that composition of a protective film can be described by the following formula: Al2O3·4AlOF·TiOF2. Solution temperature influence on properties of the coating has been studied. It was revealed that heating of a solution to 40 оС doesn’t results in essential changes of outward appearance and defense capability of coatings, while at higher temperatures (>40 оС) their defense capability has been reduced. That’s why an interval of 18–25 оС has been chosen as a working range, and it was noted that the solution heating up to 40 оС (in a summer-time, for example) is admissible. A TS-1 non-toxic passivating composition for impregnating (sealer) was developed. It has been established that the defense capability of titaniferous alloys imbued for 40–60 s in a water solution containing 2–3 g/l of TS-1 at рН = 4 and 18–30 оС, is rising almost two times more and runs up to 110 s.

This study was carried out with the support of the grant of the Russian Scientific Fund (project No 14-29-00194, Dmitry Mendeleev University of Chemical Technology of Russia).

keywords Сorrosion proofing, surface treatment, nanoceramic coatings, titaniferous coatings, hexafluorotitaniс acid, nanostructural adhesion coatings, passivating composition
References

1. Gorynin I. V. et al. Aluminievye splavy. Priminenie aluminievykh splavov (Aluminum alloys. Application of aluminum alloys). Moscow : Metallurgiya, 1978. 364 p.
2. Entsiklopediya sovremennoy tekhniki. Stroitelstvo (Encyclopaedia of modern engineering. Construction). Ed. by V. A. Kucherenko. Мoscow : Sovetskaya entsiklopediya, 1964. 544 p.
3. Zashchita aluminiya pokrytiyami: Tsentralnyy metallicheskii portal RF (Aluminum protection by coatings: Central metallic portal of the Russian Federation). Avalible at : http://metallicheckiy-portal.ru/articles/zashita_ot_korrozii_metalla/aluminii/zashita_alyminia_pokritiami/1.
4. Bhatt H. A. Replacement hexavalent chromium in automotive industry for ELV Directive. Technical paper Sur/Fin. 2002. No. 6.
5. Abrashov А. А., Grigoryan N. S., Vagramyan Т. А. et al. Steklo i Keramika = Glass and ceramics. 2014. No. 11. pp. 17–21. 6. Abrashov A., Grigoryan N., Vagramyan T. et al. Proceedings of the III International Sciences Congress “Problems and Prospects of Research in the Americas and Eurasia”. Buenos Aires, 2015. pp. 448–451.
7. Yuan M., Lu J., Kong G. et al. Surface and Coatings Technology. 2011. Vol. 205. pp. 4466–4470.
8. Jiang L., Wolpers M., Volovitch P. et al. Surface and Coatings Technology. 2012. Vol. 206. pp. 3151–3157.
9. Le Manchet S., Verche`re D., Landoulsi J. Thin Solid Films. 2012. Vol. 520. pp. 2009–2016.
10. Surface treatment method of metal material. Pat. US 0048584 A1.
11. Aluminum surface treatment agent, treatment method, and treated aluminum. Pat. EP 0812934 A1.
12. Grygoryan N. S., Akimova E. F., Vagramyan Т. А. Fosfatirovanie (Phosphatization). Мoscow : Globus, 2008. 144 p.

Full content Titaniferous protective coatings on aluminum alloys
Back