ArticleName |
Development of raw material and product sampling methods with
determination of content of non-ferrous and precious metals at concentration and metallurgical enterprises. Part 1 |
Abstract |
Russian concentration and metallurgical enterprises can not be developed without using high-efficient technologies and their strict observance. Nowadays, enterprises carry out the processing of considerable amounts of non-traditional and often low-grade raw materials, anthropogenic types of raw materials, cumulated for many years, wastes of secondary non-ferrous metals, etc. Reliability of obtained sampling result is especially important in determination of weight content of valuable components, including non-ferrous and precious metals in raw materials and its processing products. During the improvement of existing material sampling methods and development of new ones, various experiment methods are applied together with modern methods of material composition researches (scanning electronic microscopy and X-ray spectral microanalysis, the whole spectrum of existing mathematical apparatus for obtained experimental data processing). These methods take into account a great number of various factors, typical for certain production. Besides physical and chemical properties of sampled material, these factors include various types of equipment, applied for sampling and sample preparation. Institute “Gipronikel” has a considerable experience of development and certification of methods of various material sampling in Rostekhregulirovaniye (Rosstandart since 2010). Together with concentration and metallurgical enterprises, the Institute has developed the sampling methods, which urgent aspects are considered in this article on example of overflows and lump copper-nickel converter matte. |
References |
1. Trebovaniya GOKhRAN ot 25.12.2000 goda po sostavleniyu i oformleniyu godovogo metallurgicheskogo balansa dragotsennykh metallov v organizatsii, v kotoroy osushchestvlyaetsya postoyannyy gosudarstvennyy kontrol (Gokhran requirements (25.12.2000) about compiling and design of annual metallurgical balance of precious metals in the organization, where constant state control is realized). (in Russian). 2. Karpenko N. V. Oprobovanie i kontrol kachestva produktov obogashcheniya rud (Sampling and quality control of ore concentration products). Moscow : Nedra, 1987. 216 p. 3. Kozin V. Z. Oprobovanie i kontrol tekhnologicheskikh protsessov obogashcheniya (Sampling and control of technological concentration processes). Moscow : Nedra, 1985. 294 p. 4. Kozin V. Z. Oprobovanie na obogatitelnykh fabrikakh (Sampling at concentration plants). Moscow : Nedra, 1988. 287 p. 5. Kozin V. Z. Tovarnoe i operativnoe oprobovanie na obogatitelnykh fabrikakh (Marketable and efficient sampling at concentration plants). Izvestiya vuzov. Gornyy zhurnal = Proceedings of universities. Mining Journal. 2005. No. 5. pp. 86–99. 6. Sturm V., Schmitz H.-U., Reuter T., Fleige R., Noll R. Fast vacuum slag analysis in a steel works by laser-induced breakdown spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy. 2008. Vol. 63, Iss. 10. pp. 1167–1170. 7. Makiishi Noriko, Sato Shigeomi, Nagashima Hitoshi. On-site Rapid Analysis of Steelmaking Slag Using Fluorescent X-ray Analysis. JFE Giho. 2006. No. 13. pp. 48–53. 8. Rasemain W., Kreutzmann H., Kempski Сh. Risiko der Bestimmung von Metallgehalten in Elektronikschrott-Modellrechnung und statistische. Schuttgut. 2006. Vol. 12, No. 3. pp. 170–178. 9. Tarring T. Czech company Kovohute Pribram fails to feed new capacity. Metal Bulletin. 2002. No. 8669. p. 9. 10. Tokarev O. V., Kuzenkov M. V., Udalov A. E. Tekhnologii podzemnoy vyemki zapasov medno-nikelevykh rud Zhdanovskogo mestorozhdeniya v period perekhoda s otkrytogo sposoba razrabotki na podzemnyy (Technologies of underground mining of copper-nickel ore reserves (Zhdanovskoe deposit) during open-cast mining change to underground mining). Gornyi Zhurnal = Mining Journal. 2015. No. 6. pp. 60–64. 11. Ertseva L. N. Opyt primeneniya metodov rastrovoy elektronnoy mikroskopii i rentgeno-spektralnogo mikroanaliza dlya issledovaniya materialov tsvetnoy metallurgii (Experience of application of scanning electronic microscopy and X-ray spectral microanalysis methods for research of non-ferrous metallurgy materials). Tsvetnye Metally = Non-ferrous metals. 2011. No. 8/9. pp. 86–91. 12. Joseph I. Goldstein, Dale E. Newbury, Patrick Echlin, David C. Joy, et al. Rastrovaya elektronnaya mikroskopiya i rentgenospektralnyy mikroanaliz (Scanning Electron Microscopy and X-Ray Microanalysis). In two volumes. Moscow : Mir, 1984. Vol. 1. 303 p; Vol. 2. 348 p. 13. GOST 13170–80. Rudy i kontsentraty tsvetnykh metallov. Metod opredeleniya soderzhaniya vlagi (State Standard 13170–80. Ores and concentrates of nonferrous metals. Method for determination of moisture content). Introduced: 1980–07–01. Moscow : Publishing House of Standards, 1999. (in Russian). 14. GOST 14180–80. Rudy i kontsentraty tsvetnykh metallov. Metody otbora i podgotovki prob dlya khimicheskogo analiza i opredeleniya vlagi (State Standard 14180-80. Ores and concentrates of non-ferrous metals. Methods for sampling and preparation of samples for chemical analysis and determination of moisture). Introduced: 1987–07–01. Moscow : Publishing House of Standards, 1990. (in Russian). 15. OST 48-276–86. Rudy i kontsentraty tsvetnykh metallov s poputnym soderzhaniem blagorodnykh metallov. Otbor i podgotovka prob dlya opredeleniya soderzhaniya blagorodnykh metallov i vlagi (Industry standard 48-276-86. Ores and concentrates of non-ferrous metals with accompanying content of noble metals. Sampling and sample preparation for determination of noble metals and moisture content). Introduced: 1987-07–01. Moscow : Otraslevoy standart SSSR. 16 p. (in Russian). 16. Novitskiy P. V., Zograf I. A. Otsenka pogreshnostey rezultatov izmereniy (Assessment of measurement result errors). Leningrad : Energoatomizdat, 1991. 304 p. 17. P. J. Huber. Robastnost v statistike (Robust Statistics). Translated from English. Moscow, 1984. 304 p. 18. Frank R. Hampel, Elvezio M. Ronchetti, Peter J. Rousseeuw, Werner A. Stahel. Robastnost v statistike. Podkhod na osnove funktsiy vliyaniya (Robust statistics. The approach based on influence functions). Translated from English. Moscow, 1989. 512 p. 19. Glazatov A. N., Tsemekhman L. Sh., Lukashova M. V., Eroshevich S. Yu., Lazarev V. I. Usovershenstvovanie metodiki oprobovaniya otvalnogo shlaka pechey Vanyukova na Mednom zavode Otkrytogo Aktsionernogo Obshchestva “Gorno-Metallurgicheskiy Kombinat “Norilskiy nikel” (Improvement of Vanukov furnace dump slag sampling method at the Copper Plant of JSC “MMC “Norilsk Nickel”). Tsvetnye Metally = Non-ferrous metals. 2012. No. 10. pp. 39–44. 20. Glazatov A. N., Tsemekhman L. Sh., Spitsyn N. K., Kazakov A. M., Novikov M. N., Sokolov S. V. Sovershenstvovanie metodiki oprobovaniya slivov klassifikatsii na obogatitelnoy fabrike Otkrytogo Aktsionernogo Obshchestva “Kolskaya Gorno-Metallurgicheskaya Kompaniya” (Improvement of overflow sampling method at the concentration plant of JSC “Kola MMC”). Obogashchenie Rud = Mineral processing. 2010. No. 3. pp. 35–38. 21. GOST 28192–89. Otkhody tsvetnykh metallov i splavov. Metody otbora, podgotovki prob i metody ispytaniy (State Standard 28192–89. Waste of nonferrous metals and alloys. Methods of sampling, sample preparation and test methods). (in Russian). 22. Tsymbulov L. B. Sovershenstvovanie sushchestvuyushchikh i razrabotka novykh pirometallurgicheskikh tekhnologiy pererabotki nikelsoderzhashchego syrya : avtoreferat dissertatsii … doktorara tekhnicheskikh nauk (Improvement of existing pyrometallurgical technologies of nickelcontaining raw material processing and development of new ones : thesis of inauguration of Dissertation ... of Doctor of Engineering Sciences). Saint Petersburg, 2004. 48 p. 23. Glazatov A. N., Tsemekhman L. Sh., Tsymbulov L. B., Spitsyn N. K., Kovalishin Yu. S., Salamova R. V. Sovershenstvovanie sistemy vkhodnogo kontrolya faynshteyna Nadezhdinskogo Metallurgicheskogo Zavoda na Otkrytom Aktsionernom Obshchestve “Kolskaya Gorno-Metallurgicheskaya Kompaniya” (Improvement of entry control system of converter matte of Nadezhda Metallurgical Plant at JSC “Kola MMC”). Tsvetnaya metallurgiya = Non-ferrous metallurgy. 2010. No. 2. pp. 19–24. |