Название |
Technology of synthetic crystalline micro-porous titanium silicate production |
Информация об авторе |
Author 1: Name & Surname: Kalugin A. I. Company: Apatit JSC (Kirovsk, Russia) Work Position: Technical Director—Chief Engineer Scientific Degree: Candidate of Engineering Sciences Contacts: e-mail: AKalugin@phosagro.ru
Author 2: Name & Surname: Nikolaev A. I. Company: I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center, Russian Academy of Science (Apatity, Russia) Work Position: Research Manger Scientific Degree: Doctor of Engineering Sciences
Author 3: Name & Surname: Gerasimova L. G. Company: I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center, Russian Academy of Science (Apatity, Russia) Work Position: Divisional Manager Scientific Degree: Doctor of Engineering Sciences
Author 4: Name & Surname: Skryabin A. N. Company: Apatit JSC (Kirovsk, Russia) Work Position: Head of Research Center
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Реферат |
During 85 years of operation, the Khibiny apatite-nepheline ore deposits have been supplying Russia with the phosphorus-containing feedstock. Nevertheless, utilization of the compound apatite-nepheline material remains low-efficient. Apart from apatite, up to 10% of nepheline is extracted. Fines of the other minerals (aegirine, sphene, titano-magnetite) almost in full go to tailings ponds, which causes regional ecological deprivation. The lack of operating titanium deposits in Russia makes the apatite-nepheline ore a promising alternative source of titaniferous minerals such as sphene and titanomagnetite. The joint research carried out by experts of Apatit JSC and scientists of the Kola Science Center, Russian Academy of Sciences, has resulted in the development of the recovery and processing schemes enabling production of marketable sphene, titano-magnetite and aegirine concentrates. The production package developed at the Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials allows an optimum choice of technologies for the titanium and rare metal feedstock processing. The accessory minerals in the composition of the Khibiny alkaline rocks were earlier neglected in view of their small amount and complicated recovery. Discovery of new minerals was very important for understanding the ore and mineral formation processes. Pegmatitic and hydrothermal veins inside the Main Ring of the Khibiny Mountains disclosed an unusually high, even for alkaline rocks, number of mineral types (300). The article discusses the experimental results of synthesizing some equivalents of natural titanium silicates and their sorption ability. The studies were aimed at development of an innovative multipath technology for production of fine-porous titanium silicate materials from the feedstock represented by the apatite-nepheline ore dressing tailings and, first of all, sphene concentrate. |
Библиографический список |
1. Fedorov S. G., Nikolaev A. I., Brylyakov Yu. E. et al. Khimicheskaya pererabotka mineralnykh kontsentratov Kolskogo poluostrova (Chemical processing of mineral concentrates of Kola Peninsula). Apatity, 2003. 196 p. 2. Pleshakov Yu. V., Alekseev A. I., Brylyakov Yu. E., Nikolaev A. I. Tekhnologiya kompleksnogo obogashcheniya apatit-nefelinovykh rud (Technology of complex concentration of apatite-nepheline ores). Obogashchenie Rud = Mineral processing. 2004. No. 2. pp. 15–17. 3. Pleshakov Yu. V., Fedchenko V. F., Shishkin S. P., Suvorova O. V. Egirinovyy kontsentrat — tsennoe syre dlya promyshlennosti (Aegirite concentrate — valuable raw materials for industry). Obogashchenie Rud = Mineral processing. 2005. No. 5. pp. 39–41. 4. Brylyakov Yu. E., Nikolaev A. I., Gerasimova L. G. Perspektivnye napravleniya tekhnologii pererabotki kontsentratov kompleksnogo obogashcheniya apatit-nefelinovykh rud (Prospective ways of technology of processing of concentrates of complex apatite-nepheline ores concentration). Gornyi Zhurnal = Mining Journal. 2009. No. 9. pp. 62–65. 5. Kalinnikov V. T., Nikolaev A. I. Perspektivy razvitiya khimicheskikh proizvodstv na baze syrya Kolskogo poluostrova (Prospects of development of chemical productions on the basis of raw materials of Kola Peninsula). Tsvetnye Metally = Non-ferrous metals. 2011. No. 11. pp. 17–24. 6. Khomyakov A. P. Mineralogy of hyperagpaitic alkaline rocks. Oxford : Clarendon Press, 1995. 223 p. 7. Yakovenchuk V. N., Ivanyuk G. Yu., Pakhomovsky Ya. A., Menshikov Yu. P. Khibiny. Laplandia Minerals. Editor: F. Wall. Apatity, 2005. 468 p. 8. S. M. Kuznicki. Large-pored crystalline titanium molecular sieve zeolites. Patent US, No. 4853202. Filling Date: September 8, 1987. Issued Data: August 1, 1989. 9. Nikolaev A. I., Ivanyuk G. Yu., Krivovichev S. V. et al. Nanoporistye titanosilikaty: kristallokhimiya, usloviya lokalizatsii v shchelochnykh massivakh i perspektivy sinteza (Nano-porous titanium-silicates: crystal chemistry, localization conditions in alkaline massifs and synthesis prospects). Vestnik Kolskogo Nauchnogo Tsentra Rossiyskoy Akademii Nauk = Bulletin of Kola Science Center of Russian Academy of Sciences. 2010. No. 3. pp. 104–109. 10. Yakovenchuk V. N., Selivanova E. A., Ivanyuk G. Yu., Pakhomovsky Ya. A., Spiridonova D. V., Krivovichev S. V. First natural pharmacosiderite-related titanosilicates and their ion-exchange properties. Minerals as advanced materials I. Editor: S. Krivovichev. Berlin : Springer-Verlag Berlin Heidelberg, 2008. pp. 27–35. 11. Ferraris G. Heterophyllosilicates, a potential source of nanolayers for materials science. Minerals as Advanced Materials I. Editor: S. Krivovichev. Berlin : Springer-Verlag Berlin Heidelberg, 2008. pp. 157–163. 12. Nikolaev А. I., Gerasimova L. G., Maslova М. V., Spiridonova D. V., Yakovenchuk V. N., Ivanyuk G. Yu. Synthesis and properties of nano-porous titanosilicates. Journal of International Scientific Publication. 2012. Vol. 6, Рart 2. pp. 18–26. 13. Nikolaev A. I., Gerasimova L. G., Maslova M. V. Structural transformations of framework titanosilicates during thermolysis. III International workshop, 25-29 June 2013. Kirovsk, 2013. pp. 43–44. 14. Gerasimova L. G., Nikolaev A. I., Maslova M. V. et al. Sposob pererabotki titansoderzhashchego kontsentrata (Method of processing of titaniumcontaining concentrate). Patent RF, No. 2467953. Published: November 27, 2012. Bulletin No. 33. |