NOBLE METALS AND ALLOYS | |
Название | Autoclave oxidation of the solid residue of the float concentrate biooxidation |
Автор | Shneerson Ya. M., Chugaev L. V., Zhunusov M. T., Markelov A. V., Drozdov S. V. |
Информация об авторе | LLC “Gidrometallurgiya” Scientific and Research Center Ya. M. Shneerson, Chief Executive Officer, Professor, e-mail: ims@gidrometall.ru L. V. Chugaev, Leading Researcher A. V. Markelov, Researcher
M. T. Zhunusov, Head of a Science and Technology Department S. V. Drozdov, Head of a Hydrometallurgy Laboratory of the Research Center |
Реферат | Bacterial oxidation is one of the most common methods of the revelation of hard gold concentrates. CJSC “Polyus” developed the Bionord® technology — the technology of bacterial oxidation, which is used for many years. However, the bacterial method does not allow to oxidize the gold bearing sulphides completely. It is accompanied with obtaining of the considerable amounts of the elemental sulfur. It greatly increases the consumption of cyanide during the cyanidation process. A possible solution is to oxidize the elemental sulfur and residual amounts of the sulphide sulfur during the autoclave oxidation. This article presents the results of laboratory investigations in this direction. The object of research is the product of biooxidation, which contains 8.9% of elemental sulfur and 6.4% of sulphide sulfur. It is studied the influence of the process parameters (such as temperature and oxygen pressure) on the kinetics of autoclave oxidation of this material. It is shown that at the temperature of 225 оC and partial oxygen pressure of 0.5–0.7 MPa, the autoclave oxidation of the material can improve the gold recovery from 86% to 96% and decrease the cyanide consumption from several tens to 3–6 kg/t. The pilot tests of the process were held on the installation. This installation consists of 4 autoclaves, which are connected in serial. The capacity of each part is 12 liters. The results of the pilot plant tests confirm with the laboratory research. The gold recovery rate is not less than 96%, and cyanide consumption is not more than 5 kg/t. According to the results of this work, there is proposed the structural scheme of the industrial implementation of this process. |
Ключевые слова | Gold, bacterial oxidation, autoclave oxidation, elemental sulfur, sulphide sulfur, gold extraction, cyanide consumption |
Библиографический список | 1. Gericke M., Neale J. W., van Staden P. J. A Mintek perspective of the past 25 years in minerals bioleaching. Journal of The Southern African Institute of Mining and Metallurgy. 2009. Vol. 109. pp. 567–585. 2. Brierley C. L. How will biomining be applied in future? Transactions of nonferrous metals society of China. 2008. Vol. 18. pp. 1302–1310. 3. Sovmen V. K., Guskov V. N., Belyy A. V., Drozdov S. V. et al. Pererabotka zolotonosnykh rud s primeneniem bakterialnogo okisleniya v usloviyakh Kraynego Severa (Processing of the gold-bearing ores with using the bacterial oxidation in the conditions of the Far North). Novosibirsk : Nauka, 2007. 144 p. 4. Sovmen V. K., Guskov V. N. Sposob pererabotki pervichnykh zolotosulfidnykh rud (Approach of processing of the primary gold and sulfur ores). Patent RF, No. 2256712, MPK С 22 В 11/08, 03/18. Asserted 29.12.2004. Published 20.07.2005. 5. Ivanov E. I. , Sovmen V. K. Sposob izvlecheniya zolota iz upornykh zolotosoderzhashchikh rud (Approach of gold extraction from the hard gold-containing ores). Patent RF, No. 2275437, MPK С 22 В 11/08. Asserted 19.04.2005. Published 27.04.2006. 6. Silva L., Guimaraes R., Milbourne J. Process modifications to the São Bento concentrator of Eldorado Gold. Pressure Hydrometallurgy 2004. Proceedings of International Conference on the use of pressure vessels for metal extraction and recovery. 34th Annual Hydrometallurgy Meeting of CIM. Banf, Alberta, Canada, 23–27 October 2004. pp. 781–794. 7. Dymov I., Ferron C. J., Phillips W. Pilot plant evaluation of a hybrid biological leaching-pressure oxidation process for auriferous arsenopyrite/pyrite feedstocks. 34th Annual Hydrometallurgy Meeting of CIM. pp. 765–780. 8. Buketov E. A., Ugorets M. Z. Gidrokhimicheskoe okislenie khalkogenov i khalkogenidov (Hydrochemical oxidation of chalcogenes and chalcogenides). Alma-Ata : Nauka, 1975. 326 p. 9. Grinvud N., Ernsho A. Khimiya elementov. Tom 2 (Chemistry of elements. Volume 2). Moscow : Binom. Laboratoriya znaniy, 2008. 10. Laptev Yu. V., Sirkis A. L., Kolonin G. R. Sera i sulfidoobrazovanie v gidrometallurgicheskikh protsessakh (Sulfur and obtaining of sulphides in hydrometallurgical processes). Novosibirsk : Nauka, Syberian branch, 1987. 11. Spiridonov F. M., Zlomanov V. P. Khimiya khalkogenov (Chemistry of chalcogenes). Under the editorship of Yu. D. Tretyakov. Moscow, 2000. |
Language of full-text | русский |
Полный текст статьи | Получить |