ArticleName |
Application of polymer coatings to protect the external surface of municipal hot water supply pipes
against corrosion |
ArticleAuthorData |
St. Petersburg Mining University of Empress Catherine II, St. Petersburg, Russia E. I. Pryakhin, Dr. Eng., Prof., Head of the Dept. of Mazerials Science and Technology of Art Products, e-mail: Pryakhin_EI@pers.spmi.ru D. A. Pribytkova, Postgraduate Student, Dept. of Materials Science and Technology of Art Products, e-mail: pribytda@gmail.com |
Abstract |
This study presents experimental data that assess the physico-mechanical properties of a two-layer protective coating designed to enhance the corrosion resistance of district heating pipelines. The coating consists of polyurethane and epoxy enamels, each offering specific advantages. Epoxy coatings are characterized by high adhesion to metal surfaces and excellent chemical resistance, while polyurethane enamels exhibit high elasticity, resistance to ultraviolet radiation, and mechanical damage. To improve the coating’s performance characteristics and simplify the application process, a combined approach is proposed, where the first layer consists of epoxy enamel and the second of polyurethane enamel. This method integrates the benefits of both materials, ensuring reliable protection against external influences, improved operational properties, and an extended service life. The experimental results confirmed that the two-layer coating outperforms single-component alternatives in quality. The study examines key parameters such as continuity, adhesion, and mechanical resistance to impact and bending for two coating combinations: one with an epoxy base layer and a polyurethane top layer, and the other with the layers applied in reverse order. |
References |
1. Semenov A. G. Protection against corrosion of heating network pipelines. Novosti teplosnabzheniya. 2017. Vol. 207. No. 11. pp. 1–8. 2. Cole I. S., Marney D. The science of pipe corrosion: A review of the literature on the corrosion of ferrous metals in soils. Corrosion Science. 2012. Vol. 56. pp. 5–16. DOI: 10.1016/j.corsci.2011.12.00 3. Shlychkov D. I. Issues of the technical condition of existing pipeline systems. Innovatsii i Investitsii. 2020. No. 4. pp. 207–210. 4. Petrova T. A., Epishina A. D. Anti-corrosion protection of pipelines at mining and processing enterprises. Obogashchenie Rud. 2023. No. 6. pp. 52–58. 5. Litvinenko V. S. et al. Barriers to implementation of hydrogen initiatives in the context of global energy sustainable development. Journal of Mining Institute. 2020. Vol. 244. pp. 428–438. DOI: 10.31897/pmi.2020.4.421 6. Aginey R. V., Kapachinskikh Zh. Yu., Isupova E. V., Alexandrov О. Y. Analysis of approaches to de signing electrochemical protection systems for underground pipelines in Russia and abroad. Science and Technologies: Oil and Oil Products Pipeline Transportation. 2022. Vol. 12. No. 5. pp. 480–488. 7. Aginey R. V., Firstov A. A. Improvement of the method for assessing bending stresses in the wall of an underground pipeline. Zapiski Gornogo instituta. 2022. Vol. 257. pp. 744–754. DOI: 10.31897/PMI.2022.64 8. Kotyukov P. V. Features of the assessment of vulnerability and destruction of structural materials of transport structures in the underground space of St. Petersburg. Zapiski Gornogo instituta. 2010. Vol. 186. pp. 22–26. 9. Issa B., Bazhin V. Yu., Karapetyan K. G. The role of multi-phase metal content in corrosion and premature failure mitigation of steel equipment in oil refineries. Part 1. CIS Iron and Steel Review. 2023. Vol. 25. pp. 90–96. 10. Mustafin F. M. Review of methods of pipeline protection against corrosion by insulating coatings. Neftegazovoe delo. 2003. No. 1. pp. 1–24. 11. Petkova A. P., Zlotin V. A. Analysis of the efficiency of reducing hydrogen losses in a pipeline made of various austenitic stainless steels. Chernye Metally. 2024. No. 9. pp. 50–54. 12. Vologzhanina S. A., Ermakov B. S., Ermakov S. B., Khuznakhmetov R. M. Relationship between operating conditions and the emergence of nano- and ultradispersed grain boundary defects in welded joints. Tsvetnye Metally. 2023. No. 8. pp. 80–85. 13. Kim J. G., Kim Y. W., Kang M. C. Corrosion characteristics of rigid polyurethane thermally insulated pipeline with insulation defects. Corrosion. 2002. Vol. 58, Iss. 2. pp. 175–181. DOI: 10.5006/1.3277318 14. Petkova A. P., Gorbatyuk S. M., Sharafutdinova G. R. et al. Selection of materials and technologies for the electrochemical synthesis of sodium ferrate. Metallurgist. 2024. Vol. 68. pp. 449–459. DOI: 10.1007/s11015-024-01747-w 15. Brylov I. F. Determination of the corrosion rate of pipe steels in suspensions of soils of various compositions. Izvestiya vuzov. Severo-Kavkazskiy region. Tekhnicheskie nauki. 2011. No. 3. pp. 108–110. 16. Pryakhin E. I., Azarov V. A. Comparative analysis of the use of epoxy and fluoroplastic polymer compositions as internal smooth coatings of the inner cavity of steel main gas pipelines. CIS Iron and Steel Review. 2024. Vol. 28. pp. 93–98. 17. Kiselev V. G., Ruzich E. N. Dielectric coatings and their influence on corrosion protection of the outer surface of underground pipelines. Problemy energetiki. 2018. Vol. 20. No. 1–2. pp. 80–89. 18. Goldobina L. A., Orlov P. S. Analysis of causes of corrosion damage to underground pipelines and new solutions to improve the corrosion resistance of steel. Zapiski Gornogo instituta. 2016. Vol. 219. No. 3. pp. 459–464. 19. Prokopchuk N. R., Syrkov A. G., Klyuev A. Yu., Laptik I. O. Mechanical properties of epoxy coatings on metal enhanced with nanoparticles of different nature. Tsvetnye Metally. 2023. No. 8. pp. 25–29. 20. Kausar A. Performance of corrosion protective epoxy blend-based nanocomposite coatings: a review. Polymer-Plastics Technology and Materials. 2019. Vol. 59, Iss. 6. pp. 658–673. DOI: 10.1080/25740881.2019.1673410 21. Baranovskaya L. P., Bernenko N. O. Dependence of coating adhesion on roughness. Aktualnye problemy aviatsii i kosmonavtiki. 2017. No. 13. pp. 760–762. 22. Dozhdelev A. M. et al. Laser cleaning of metal products. Mezhdunarodny zhurnal gumanitarnykh i estestvennykh nauk. 2022. Vol. 75. No. 12-2. pp. 123–125. DOI: 10.24412/2500-1000-2022-12-2-123-125 23. Veyko V. P., Kishalov A. A., Mutin T. Yu., Smirnov V. N. Prospects for industrial applications of laser cleaning of materials. Nauchno-tekhnicheskiy vestnik informatsionnykh tekhnologiy, mekhaniki i optiki. 2012. Vol. 79. No. 3. pp. 50–54. 24. Song J., Huang H., Wang X. et al. Status and prospects of surface texturing: design, manufacturing and applications. Surface Science and Technology. 2023. Vol. 1, Iss. 21. pp. 1–29. DOI: 10.1007/s44251-023-00022-5 25. Amiaga J., Ramos-Velazquez A., Vologzhanina S. Laser oxide reduction duting multipass relief forming on carbon steel surface. Opt. Quant. Electron. 2023. Vol. 522, Iss. 55. pp. 1–15. DOI: 10.1007/s11082-023-04688-x 26. Dolgalev S. G., Dolgaleva O. A., Chernousova N. V., Andrianova G. P. Dependence of the level of internal stresses in an epoxy coating on the adhesive layers used. Vestnik Kazanskogo tekhnologicheskogo universiteta. 2010. No. 12. pp. 446–451. 27. Starikova E. Yu., Feyler L. A. Protective phosphate coatings of metals. Vestnik Kuzbasskogo gosudarstvennogo tekhnicheskogo universiteta. 2020. Vol. 142. No. 6. pp. 46–50. 28. Shutova A. L. et al. Epoxy paints and varnishes for heating network pipelines. Trudy BGTU. Seriya 2: Khimicheskie tekhnologii, Biotekhnologiya, Geoekologiya. 2017. Vol. 199. No. 2. pp. 96–101. 29. Junwei Chang et. al. Corrosion resistance of tannic acid, d-limonene and nano-ZrO2 modified epoxy coatings in acid corrosion environments. Journal of Materials Science & Technology. 2021. Vol. 65. pp. 137–150. DOI: 10.1016/j.jmst.2020.03.081 30. Pryakhin E. I., Pribytkova D. A. The influence of the quality of surface preparation of pipes for heating networks on their corrosion resistance during operation in underground conditions. Chernye Metally. 2023. No. 11. pp. 97–102. 31. GOST 15140–78. Paintwork materials. Methods for determination of adhesion. Introduced: 01.01.1979. 32. GOST 6806–2024. Coating materials. Method for determination of coating flexibility in bending. Introduced: 01.07.2024. 33. GOST 4765–73. Paint and lacquer materials. Method for determination of impact resistance. Introduced: 01.07.1974. 34. GOST 8832–76. Paintwork materials. Methods for formation of paint coating for testing. Introduced: 01.01.1977. 35. GOST 34395–2018. Paint materials. Spark test method for continuity inspection of dielectric coatings on conductive substrates. Introduced: 01.01.2019. |