Название |
Effect of quenching temperature on the structure
formation, liquation processes, microhardness of structural constituents and hardness
of alloy AM4.5Cd modified with cerium |
Информация об авторе |
Pacific National University, Khabarovsk, Russia
N. A. Slavinskaya, Lecturer of Higher School of Industrial Engineering, Polytechnic Institute, e-mail: 010763@pnu.edu.ru H. Ri, Professor of Higher School of Industrial Engineering, Polytechnic Institute, Doctor of Technical Sciences, e-mail: 000396@pnu.edu.ru E. Н. Ri, Head of Higher School of Industrial Engineering, Polytechnic Institute, Doctor of Technical Sciences, Professor, e-mail: erikri999@mail.ru A. S. Zhivetev, Associate Professor of Higher School of Industrial Engineering, Polytechnic Institute, Candidate of Technical Sciences, e-mail: 007881@pnu.edu.ru |
Реферат |
The paper presents the studies on the effect of quenching temperature during artificial aging (at 155 oС and holding time of 4 h) on the structure formation, character of the distribution of elements in structural constituents and their microhardness, hardness of alloy AM4.5Cd modified with cerium (0.2 % (wt.)). The authors have determined that higher quenching temperature and subsequent artificial aging contributed to coarsening of structural constituents: α-solid solution, intermetallic phases and eutectics. Electron microscopy and X-ray microanalysis methods were applied to identify structures at various quenching temperatures. Content of copper and manganese varies unevenly. The analysis showed two types of α-solid solutions (α1 and α2) with different chemical compositions. Content of Cu and Mn, % (at.): 2.0 Cu and 0.25 Mn in α1-solid solution shows no changes up to a quenching temperature of 585 oС, solubility of alloying elements in α2-solid solution varies according to the extremal dependence, demonstrating maximum values of copper (3.5 % (at.)) and manganese (3.5 % (at.)) at a quenching temperature of 565 oС. Every value of quenching temperature (535, 545, 565, 585, and 605 oС, respectively) was attributed to intermetallic phases of certain stoichiometry, mostly aluminides of titanium AlxTiyiCezCdvCuw and copper AlxCuyMnzCdv. The authors identified relations between compositions of α-solid solutions, intermetallic compounds and their microhardness, and quenching temperature. Thus, an increase in quenching temperature to 545 oС contributes to an increase in hardness of alloy AM4.5Cd + 0.2 % (wt.) Ce to 104 HB, and a sharp decrease to 60 HB at 605 oС. |
Библиографический список |
1. Ma Z., Zhan L., Liu C., Xu L. et al. Stress-level-dependency and bimodal precipitation behaviors during creep ageing of Al — Cu alloy: experiments and modeling. International Journal of Plasticity. 2018. Vol. 110. pp. 183–201. 2. Wang P., Deng L., Prashanth K. G., Pauly S. et al. Microstructure and mechanical properties of Al – Cu alloys fabricated by selective laser melting of powder mixtures. Journal of Alloys and Compounds. 2018. Vol. 735. pp. 2263–2266. 3. Znamensky L. G., Solodyankin A. A., Polinovsky V. B. High-precision casting of aluminum alloys and applying nanostructured materials for the aircraft industry. Voenny nauchno-praktichesky vestnik. 2020. No. 2. pp. 49–54. 4. Stetsenko V. Yu., Rivkin A. I., Gutev A. P., Konovalov R. V. Modification of silumins with fine-crystalline aluminum alloys. Bulletin of Sukhoi Gomel State Technical University. 2009. No. 1. pp. 21–24. 5. Skachkov V. M., Yatsenko S. P. Modification of aluminum alloys with rare metals – the basis for advanced materials in construction and transport. Nanotechnologies in Construction: a Scientific Internet Journal. 2016. Vol. 8, No. 3. pp. 60–69. 6. Yashin V. V., Aryshensky E. V., Drits A. M., Grechnikov F. V. et al. Effect of scandium on the microstructure of the Al – Cu – Mn – Mg – Hf – Nb alloy. Fizika metallov i metallovedenie. 2021. Vol. 122, No. 10. pp. 1033– 1041. 7. Laponogova P. A., Kolisova M. V., Goncharov A. V., Dzyuba G. S. Applying scandium for modifying aluminum alloys. Metallurgiya mashinostroeniya. 2020. No. 3. pp. 13, 14. 8. Ri H., Slavinskaya N. A. Modification of casting aluminum alloy AM4.5Cd (VAL10) with scandium. Liteyshchik Rossii. 2019. No. 11. pp. 13–19. 9. Duyunova V. A., Trapeznikov A. V., Leonov A. A., Koreneva E. A. Modifying cast aluminum alloys (review). Trudy VIAM. 2023. No. 4. pp. 14–26. 10. Chegodaev D. A., Antonov M. M. Study on the effect of modifying molten metal on technological and mechanical properties of products from alloy AK7pch. Proceedings of international scientific and practical conferences. Ed. by A. A. Korotkikh. 2018. pp. 349–353. 11. Amer S. M., Barkov R. Yu., Prosviryakov A. S., Pozdnyakov A. V. Structure and properties of new cast heat-resistant alloys based on Al – Cu – Y and Al – Cu –Er. Fizika metallov i metallovedenie. 2021. Vol. 122, No. 9. pp. 977–983. 12. GOST 1583–93. Aluminium casting alloys. Specifications. Introduced: 01.01.1997. 13. GOST 4784–97. Aluminium and wrought aluminium alloys. Grades. Introduced: 01.07.2000. 14. Belov N. A., Alabin A. N. Advanced aluminum alloys of higher heat resistance for the aircraft industry as a potential option to steels and cast irons. Collection of reports of the conference “Materials in mechanical engineering”. 2010. Vol. 2. pp. 50–54. 15. Ri H., Ri E. Kh., Zernova T. S. et al. Conditioning agent. Patent RF, No. 2521915. Applied: 28.11.2012. Published: 10.07.2014. 16. Xiao-hui Ao, Shu-ming Xing, Bai-shui Yu, Qing-you Han. Effect of Ce addition on microstructures and mechanical properties of A380 aluminum alloy prepared by squeeze-casting. International Journal of Minerals, Metallurgy and Materials. 2018. Vol. 25, No. 5. pp. 553–564. 17. Qinglin Li, Tiandong Xia, Yefeng Lan, Wenjun Zhao et al. Effect of rare earth cerium addition on the microstructure and tensile properties of hypereutectic Al – 20 % Si alloy. Journal of Alloys and Compounds. 2013. Vol. 562. pp. 25–32. 18. Xianchen Song, Hong Yan, Xiaojun Zhang. Microstructure and mechanical properties of Al –7 Si – 0.7Mg alloy formed with an addition of (Pr + Ce). Journal of Rare Earths. 2017. Vol. 35, No. 4. pp. 412–418. 19. Xiao D. H., Wang J. N., Ding D. Y., Yang H. L. Effect of rare earth Ce addition on the microstructure and mechanical properties of an Al – Cu – Mg – Ag alloy. Journal of Alloys and Compounds. 2003. Vol. 352, Iss. 1-2. pp. 84–88. 20. Ri E. Kh., Ri H., Khimukhin S. N., Ermakov M. A., Khimukhin T. S. Production of aluminum alloys modificator from ligature. Journal of Engineering and Applied Sciences. 2018. Vol. 13, No. 4. pp. 1265–1271. |