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MATERIALS SCIENCE
Название Phase composition, functional properties and hemolytic activity of titanium nickelide synthesized in nitrogen medium
DOI 10.17580/tsm.2023.09.07
Автор Shishelova A. A., Marchenko E. S., Baygonakova G. A., Yasenchuk Yu. F.
Информация об авторе

National Research Tomsk State University, Tomsk, Russia:

A. A. Shishelova, Undergraduate Student, e-mail: arina.sh9906@gmail.com
E. S. Marchenko, Head of the Superelastic Biointerfaces Laboratory, Associate Professor, Doctor of Physics and Mathematics Sciences
G. A. Baygonakova, Senior Researcher, Candidate of Physics and Mathematics Sciences
Yu. F. Yasenchuk, Senior Researcher

Реферат

Titanium nickelide alloys are widely used as implant material. Porous TiNi alloys are normally fabricated by self-propagating high-temperature synthesis in argon medium. Air present in the reaction chamber may lead to an increased concentration of oxynitrides at the surface of the porous TiNi alloy and thus raise its cytocompatibility. The paper examines the effect of nitrogen on the functional properties, phase composition and hemolytic activity of porous TiNi alloy. It was found that the presence of interstitial phases – such as Ti4Ni2N(O) — has no impact on the nature of martensitic transformations caused by the changing temperature. A single-phase martensitic transformation B2↔B19' takes place in the porous TiNi alloy synthesized in nitrogen medium with some oxygen present. Having studied the shape memory effect of the porous TiNi alloy, the authors conclude that the manifestation of inelastic reversible strain of the porous alloy may be constrained by the structural inhomogeneity of the matrix of porous specimens, as well as due to the emergence of brittle interstitial phases of Ti2Ni + Ti4Ni2N(O) and TiNi3 but cannot be completely suppressed by them. Porous TiNi alloys synthesized in nitrogen medium have a lower hemolytic index and a higher cytocompatibility.
This research was carried out as part of Governmental Assignment of the Ministry of Education and Science of Russia; Project No. FSWM-2020-0022.

Ключевые слова titanium nickelide, self-propagating high-temperature synthesis, X-ray spectral analysis, differential scanning calorimetry, shape memory effect, martensitic transformations, hemolytic activity, cytocompatibility
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