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HEAVY NON-FERROUS METALS
Название Removing copper and nickel from contaminated water with vermiculite-sungulite materials
DOI 10.17580/tsm.2021.02.05
Автор Mosendz I. A., Kremenetskaya I. P., Novikov A. I., Tereshchenko S. V.
Информация об авторе

I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials of the Russian Academy of Sciences Kola Science Center, Apatity, Russia:

I. A. Mosendz, Postgraduate Student, e-mail: ia.mosendz@ksc.ru
I. P. Kremenetskaya, Senior Researcher
A. I. Novikov, Junior Researcher

 

Murmansk Arctic State University, Murmansk, Russia:

S. V. Tereshchenko, Head of the Department of Mining, Earth Sciences and Environmental Engineering

Реферат

The environmental impact of non-ferrous metallurgy sites is a well-studied and thoroughly described phenomenon characterizing industrially developed areas. New techniques are being developed and adopted to help reduce the amount of metal compounds released in the environment by the industry. The so-called fugitive sources of pollution, which include polluted areas surrounding industrial sites, have been a recent focus of attention. This paper considers the possibility to use vermiculite-sungulite materials obtained by concentration of tailings produced by a phlogopite mine in Kovdor (Murmansk Region) as a sorption material to be used for removing heavy metals from contaminated ponds of the Monchegorsk Industrial Area in the Murmansk Region. A series of experiments has been conducted during which sampled water was treated with vermiculite-sungulite materials. This sorption treatment technique was established to be efficient. Some resultant solutions have residual concentrations of metals <10 mcg/L, with the purification efficiency exceeding 85%. The factor determining the process of removing nickel and copper from contaminated water includes pH, which is reached as a result of water interacting with the above materials. In the equilibrium state, provided the рН level in the system is maintained above 8.5, vermiculite-sungulite materials can keep metals sorbed thus preventing their migration from the sorption layer. The findings show that due to the use of finely dispersed materials the concentrations of copper and nickel can be lowered from 10 mg/L to a few micrograms. This research study was funded and supported by Kola MMC.

Ключевые слова Vermiculite, sungulite, contamination, copper, nickel, heavy metals, water purification
Библиографический список

1. Ghaderi A., Abduli M., Karbassi A. et al. Evaluating the effects of fertilizers on bioavailablemetallic pollution of soils, case study of Sistan farms. Iran. International Journal of Environmental Research. 2012. No. 6. pp. 565–570.
2. Govind P., Madhuri S. Heavy metals causing toxicity in animals and fishes. Research Journal of Animal, Veterinary and Fishery Sciences. 2014. No. 2. pp. 17–23.
3. Bastami K. D., Neyestani M. R., Shemirani F. et al. Heavy metal pollution assessment in relation to sediment properties in the coastal sediments of the southern Caspian Sea. Marine Pollution Bulletin. 2015. Vol. 92. pp. 237–243.
4. Xu G., Pei S., Liu J. et al. Surface sediment properties and heavy metal pollution assessment in the near-shore area, North Shandong Peninsula. Marine Pollution Bulletin. 2015. Vol. 95. pp. 395–401.
5. Singh U. K., Kumar B. Pathways of heavy metals contamination and associated human health risk in Ajay River Basin, India. Chemosphere. 2017. Vol. 174. p. 183.
6. Wu B., Song J., Li X. Evaluation of potential relationships between benthic community structure and toxic metals in Laizhou Bay. Marine Pollution Bulletin. 2014. Vol. 87. pp. 247–256.
7. Suresh G., Ramasamy V., Sundarrajan M., Paramasivam K. Spatial and vertical distributions of heavy metals and their potential toxicity levels in various beach sediments from high-background-radiation area, Kerala, India. Marine Pollution Bulletin. 2015. Vol. 91. pp. 389–400.
8. Yang X., Yuan X., Zhang A. et al. Spatial distribution and sources of heavy metals and petroleum hydrocarbon in the sand flats of Shuangtaizi estuary, Bohai Sea of China. Marine Pollution Bulletin. 2015. Vol. 95. pp. 503–512.
9. Monferran M. V., Garnero P. L., Wunderlin D. A., de los Angeles Bistoni M. Potential human health risks from metals and As via Odontesthes bonariensis consumption and ecological risk assessments in a eutrophic lake. Ecotoxicology and Environmental Safety. 2016. Vol. 129. pp. 302–310.
10. Kremenetskaya I. P., Lashchuk V. V., Volochkovskaya E. Yu. et al. A magnesia-silicate reagent for treating natural water from heavy metals emitted from the Kola Mining and Metallurgical Company (Monchegorsk area). Tsvetnye Metally. 2012. No. 7. pp. 35–40.
11. Dias N. C., Steiner P. A., Braga M. C. B. Characterization and modification of a clay mineral used in adsorption tests. Journal of Minerals and Materials Characterization and Engineering. 2015. Vol. 3. pp. 277–288.
12. Kremenetskaya I. P., Korytnaya O. P. Vasilieva T. N. A reagent locking up heavy metals contained in serpentine bearing overburden rock. Vodoochistka. Vodopodgotovka. Vodosnabzhenie. 2008. No. 4. pp. 33–40.
13. Kremenetskaya I. P., Alekseeva S. A., Rukhlenko E. D. et al. Materials designed to protect the environment from phlogopite mining waste. Ekologiya i promyshlennost Rossii. 2015. Vol. 19, No. 2. pp. 18–23.
14. Krishnani K. K., Meng X., Christodoulatos C., Boddu V. M. Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk. Journal of Hazardous Materials. 2008. Vol. 153, No. 3. pp. 1222–1234.
15. Leyva-Ramos R., Bernal-Jacome L. A., Acosta-Rodriguez I. Adsorption of cadmium (II) from aqueous solution on natural and oxidized corncob. Separation and Purification Technology. 2005. Vol. 45, No. 1. pp. 41–49.
16. Tan G., Yuan H., Liu Y., Xiao D. Removal of lead from aqueous solution with native and chemically modified corncobs. Journal of Hazardous Materials. 2010. Vol. 174. pp. 740–745.
17. Vimala R., Das N. Biosorption of cadmium (II) and lead (II) from aqueous solutions using mushrooms: a comparative study. Journal of Hazardous Materials. 2009. Vol. 168. pp. 376–382.

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