Журналы →  Tsvetnye Metally →  2017 →  №2 →  Назад

BENEFICATION
Название Flotation of gold-bearing ores of non-ferrous metals using the acetylene alcohol based reagents
DOI 10.17580/tsm.2017.02.01
Автор Yushina T. I., Malyshev O. A., Shchelkunov S. A.
Информация об авторе

Mining Institute of National University of Science and Technology “MISiS”, Chair “Dressing and Processing of Minerals and Technogenic Raw Materials”, Moscow, Russia:
T. I. Yushina, Professor, Acting Head of a Chair, e-mail: yuti62@mail.ru

 

LLC “Innovatsionnyy resurs”, Moscow, Russia:
O. A. Malyshev, Chief Executive Officer, e-mail: omalyshev57@mail.ru
S. A. Shchelkunov, Head of Chemical Progects

Реферат

This paper considers the flotation properties of collecting and foaming acetylene alcohol based agents DMIPEK (ДМИПЭК) and DK-80 (ДК-80). The basic formulas and methods of flotation agent obtaining are given, and their flotation behavior peculiarities are shown. During the flotation of sulfide gold-bearing non-ferrous metal ores, the reagents DMIPEK and DK-80 show the properties of selective additional foaming and high-active collectors. These reagents were applied during the flotation of copper and copper-zinc gold-bearing ores of New Sibay, Nizhnaya Zalezh and Mayskoe deposits and gold-bearing ore of Akabakai Mining and Processing Plant. Results of investigation of this application are shown in this paper. Usage of the reagents DMIPEK and DK-80 increases the metal extraction in concentrates. Finding the reasons of extraction increase needed the quantum-chemical calculations of mechanism and force of the reagent DMIPEK interacting with non-ferrous metal sulfides, which were carried out by defining the stabilization energy of the forming complexes. The acetylene alcohol based reagents DMIPEK and DK-80 passed the laboratory and pilot testings as selective collectors during the flotation of sulfide ores of non-ferrous and noble metals.
This scientific work was carried out with the financial participation of the Federal Target Program of the Ministry of Education and Science of the Russian Federation, project No. RFMEFI57514X0085 “Combined technology of complex processing of complex ores and technogenic raw materials of nonferrous and noble metals. The Federal Target Program “Investigations and developments by the priority ways of development of the scientific and technological complex of Russia for the period of 2014–2020”.

Ключевые слова Flotation, sulfides, gold-bearing ores, acetylene-bearing alcohols, dimethyl(isopropenylethynyl)carbinol, DK-80, foaming collectors, π-complexes
Библиографический список

1. Abramov A. A. Flotation methods of concentration. Third edition, revised and enlarged. Moscow : Izdatelstvo MGGU, 2008. 710 p.
2. Flotation paradox. CREON. URL : http://www.creonenergy.ru/news/post_relizy/detailPost.php?ID=109973 (дата обращения 22.02.2017)
3. Chanturiya V. A., Vaysberg L. A., Kozlov A. P. Promising trends in investigations aimed at all-round utilization of mineral raw materials. Obogashchenie Rud. 2014. No. 2. pp. 3–9.
4. Bocharov V. A., Ignatkina V. A., Chanturiya E. L., Yushina T. I. Technologies of complex processing of refractory pyritic ores and pyrite technogenic products with extraction of non-ferrous and rare metals. Tsvetnye Metally. 2016. No. 9. pp. 16–20. DOI: 10.17580/tsm.2016.09.01.
5. Bogdanov O. S., Maksimov I. I., Podnek A. K., Yanis N. A. Theory and technology of ore flotation. Moscow : Nedra, 1990. 363 p.
6. Chanturiya V. A. New technologies of comprehensive recovery of valuable components from minerals: Current status and further progress. Geologiya rudnykh mestorozhdeniy. 2007. Vol. 49, No. 3. pp. 235–242.
7. Abramov A. A. Flotation. Collecting agents: collection of works. Moscow : Gornaya kniga, 2012. 656 p.
8. Abramov A. A. Theory of creation of innovation flotation technologies. Part III. Theory of intensification of technological processes of flotation. Tsvetnye Metally. 2013. No. 4. pp. 12–17.
9. Arsentev V. A., Gorlovskiy S. I., Ustinov I. D. Complex effect of flotation agents. Moscow : Nedra, 1990. 363 p.
10. Melik-Gaikazyan V. I., Emel’yanov V. M., Emel’yanova N. P., Moiseev A. A., Emel’yanov V. V., Yushina T. I. Investigation into the Froth Flotation and selection of Reagents on the Basis of the Mechanism of Their Action: Report 2. A Comparison of Flotation Properties of Millimeter, Micrometer, and Nanometer Bubbles Based on Equations of Capillary Physics. Part One. Russian Journal of Non-Ferrous Metals. 2011. Vol. 52, No. 6. pp. 329–336.
11. Melik-Gaikazyan V. I., Emel’yanov V. M., Emel’yanova N. P., Moiseev A. A., Emel’yanov V. V., Yushina T. I. Investigation into the Froth Flotation and selection of Reagents on the Basis of the Mechanism of Their Action: Report 2. A Comparison of Flotation Properties of Millimeter, Micrometer, and Nanometer Bubbles Based on Equations of Capillary Physics. Part Two. Russian Journal of Non-Ferrous Metals. 2011. Vol. 52, No. 6. pp. 463–468.
12. Kulberg L. M. Organic reactives in analytical chemistry. Moscow : Goskhimizdat, 1950. 260 p.
13. Kondratev S. A., Ryaboy V. I. Dithiophosphates collecting ability estimation and its relationship to selectivity of valuable component recovery. Obogashchenie Rud. 2015. No. 3. pp. 25–30. DOI: 10.17580/or.2015.03.04.
14. Kariman A., Rezaei B., Masoumi A. The effect of mixed collectors in rougher flotation of sungun copper. Life Science Journal. 2013. No. 10. pp. 268–272.
15. Bocharov V. A., Ignatkina V. A. Technology of dressing of gold-bearing raw materials. Moscow : “Ore and Metals” Publishing House, 2003. 408 p.
16. Bocharov V. A., Mantsevich M. I., Zakharova B. A. State and prospects of development of complex processing technology of non-ferrous metal ores. Tsvetnye Metally. 2008. No. 2. pp. 65–71.
17. Yushina T. I., Malyshev O. A., Shсhelkunov S. A., Khrustalev D. P. Peculiarities of the DC-80 reagent based on acethylenic alcohols effect in flotation processes. Non-ferrous Metals. 2016. No. 2. pp. 7–11. DOI: 10.17580/nfm.2016.02.02.
18. Sabanova M. N., Gusev A. A., Shchelkunov S. A., Malyshev O. A. The results of “DMIPEK” reagent application in flotation benefication of copper and copper-zinc ores. Obogashchenie Rud. 2012. No. 5. pp. 33, 34.
19. Glembotskiy A. G., Abramov A. A., Podvishenskiy N. S. et al. Industrial testings of the reagent MIG-4E (MIG-4E) during the concentration of bysmuth-silver ores. Tsvetnaya metallurgiya. 1970. No. 3. pp. 8, 9.
20. Shubov L. Ya., Ivankov S. I. Patented flotation agents. Moscow : Nedra, 1992. 362 p.
21. Shchelkunov S. A., Malyshev O. A. Foamer for mineral flotation and method of its obtaining. Patent RF, No. 2552430. Applied: 16.12.2013. Published: 10.12.2015.
22. Shchelkunov S. A., Malyshev O. A. Dimethyl(isopropenylethynyl)carbinol — an efficient non-ionogenic foaming collector. Tsvetnaya metallurgiya. 2008. No. 3. pp. 7–12.
23. Kurkov A. V., Pastukhova I. V. New approaches for the choice of flotation agents for processing of complex ores. New technologies of dressing and complex processing of complex natural and anthropogenic mineral resources. Materials of International meeting “Plaksin readings — 2011”. Verkhnyaya Pyshma, 19–24 September 2011. pp. 33–36.
24. Glembotsky A., Kasianova H., Gurvich S., Kvale O. Collecting properties of flothers. Is their prediction possible? Proceedings XVII IMPC. Dresden, September, 1991. pp. 23–28.
25. Abramov A. A. Theory of creation of innovation flotation technologies. Part VI. Theory of increasing of selectivity of activities of reagents-frothers during the flotation. Tsvetnye Metally. 2013. No. 11. pp. 34–39.
26. Ryaboy V. I. Creation and application of more efficient reagents on the basis of physical and chemical interpretations. Obogashchenie Rud. 2002. No. 1. pp. 19–23.

Language of full-text русский
Полный текст статьи Получить
Назад