Название |
A new look at the choice of processing technology of ingrained oxide-sulfide platinum-copper-nickel ores
|
Информация об авторе |
LLC “POLAR engineering”, Moscow, Russia:
V. M. Paretskiy, Chief Metallurgist A. M. Ptitsyn, Chief Engineer, e-mail: metago_ptitsyn@mail.ru
LLC “Institute “Gipronickel”, Saint Petersburg, Russia: L. Sh. Tsemekhman, Chief Researcher L. B. Tsymbulov, Head of Pyrometallurgical Laboratory |
Реферат |
Finely-ingrained refractory sulfide-oxide copper-nickel ores, containing a large amount of platinum group metals, are considered as platinum-palladium ores, instead of copper-nickel ores. This principle became the basis of technology of two-stage smelting of these ores in two-zone Vanyukov furnace, providing the higher extraction of platinum group metals, in comparison with the concentration-metallurgical scheme. On the basis of literature review and results, carried out before the experimental investigations of platinum group metal distribution between the products of pyrometallurgical processing of copper-nickel concentrates, there was carried out the adaptation of thermodynamic model of the software complex FactSage 6.3, connected basically with the accounting of mechanical loss of platinum group metals with dump slags. On its basis, there were defined the coefficients of distribution of platinum group metals between the smelting products of Taimyr oxide-sulfide ores, taking into account the influence of the change of slag and matte mass ratio on distribution of non-ferrous and platinum group metals, because the mass ratio of obtained matte and slag are the main difference of this ore melting type. The forecast calculations of material and energetic balances were carried out. The process flow diagram was designed, and the initial data were made for the development of technological regulations of processing of 1 mln tone of Taimyr oxide and sulfide ore per year. Preliminary technical-economic assessment of created production was carried out. |
Библиографический список |
1. Malema M. T., Legg A. C. Recent improvements at the BCL smelter. Southern African Pyrometallurgy 2006 International Conference. Editor: R. T. Jones. Johannesburg, 5–8 March 2006. Johannesburg : Southern African Institute of Mining and Metallurgy, 2006. pp. 215–231. 2. Davenport W. G., Jones D. M., King M. J., Partelboeg E. H. Flash smelting: analysis, control and optimization. Warrendale : TMS, 2000. pp. 11–17, 41–53. 3. Warner A. E. M., Díaz C. M., Dalvi A. D., Mackey P. J., Tarasov A. V., Jones R. T. JOM world nonferrous smelter survey, part IV: Nickel: Sulfide. JOM. 2007. Vol. 59, No. 4. pp. 58–72. 4. Tsemekhman L. Sh., Fomichev V. V., Ertseva L. N., Kaytmazov N. G., Kozyrev S. M., Maksimov V. I., Shneerson Ya. M., Dyachenko V. T. Atlas mineralnogo syrya, tekhnologicheskikh promyshlennykh produktov i tovarnoy produktsii Zapolyarnogo filiala otkrytogo aktsionernogo obshchestva Gorno-metallurgicheskiy kombinat “Norilskiy nikel” (Atlas of mineral raw materials, technological industrial products and marketable products of the Polar Division of MMC “Norilsk Nickel”). Moscow : “Ore and Metals” Publishing House, 2010. 336 p. 5. Kotlyar Yu. A., Meretukov M. A., Strizhko L. S. Metallurgiya blagorodnykh metallov : uchebnik (Metallurgy of noble metals : tutorial). In two volumes. Volume 2. Moscow : MISiS; “Ore and Metals” Publishing House, 2005. p. 213. 6. Crundwell F. К., Moats M. S., Ramachandran V., Robinson T. G., Davenport W. G. Chapter 17 — Smelting of nickel sulfide concentrates by roasting and electric furnace smelting. Extractive metallurgy of nickel, cobalt and platinum group metals. Amsterdam : Elsevier, 2011. pp. 199–214. 7. Salt B., Cerilli E. Converter aisle improvements at Xstrata Nickel’s Sudbury smelter. Proceedings of International Symposium “Nickel and Cobalt 2009”. Sudbury, Canada, 23–26 August 2009. pp. 333–349. 8. Cole S., Ferron J. A Review of the Beneficiation and Extractive Metallurgy of the Platinum-Group Elements, Highlighting Recent Process Innovations. The Geology, Geochemistry, Mineralogy and Mineral Beneficiation of the Platinum-Group Elements. Editor: L. J. Cabri. Ontario : Canadian institute of mining, Metallurgy and petroleum, 2002. pp. 811–841. 9. Knyazev M. V., Ryabko A. G., Tsymbulov L. B., Tsemekhman L. S. Two-Zone Vaniukov Furnace: New Potential Copper and Nickel Production. Advanced Processing of Metals and Materials (Sohn International Symposium). Vol. 8. International Symposium on Sulfide Smelting 2006. Vancouver : TMS, 2010. pp. 327–334. 10. Tsymbulov L. B., Knyazev M. V., Tsemekhman L. Sh., Ryumin A. A., Maksimov D. B. Opytno-promyshlennye ispytaniya tekhnologii pererabotki briketirovannogo medno-nikelevogo kontsentrata v dvukhzonnoy pechi Vanyukova (Pilot testings of processing technology of briquetted copper-nickel concentrate in two-zone Vanukov furnace). Tsvetnye Metally = Non-ferrous metals. 2008. No. 6. pp. 30–36. 11. Tsymbulov L. B., Knyazev M. V., Tsemekhman L. Sh. et al. Pilot testing of a process treatment of Ni-containing copper concentrate after high-grade matte separation resulting in blister copper production in two-zone Vaniukov furnace. Proceedings of the sixth international Copper-Cobre Conference, The Carlos Diaz Symposium on Pyrometallurgy. Toronto, Ontario, Canada, 25–30 August 2007. Vol. III, Book 1. pp. 397–409. 12. Tsymbulov L. B. Assessment of slag and copper equilibrium in Vaniukov two-zone converter. Canadian Metallurgical Quarterly. 2011. Vol. 50, No. 2. pp. 127–134. |