ENVIRONMENTAL PROTECTION TECHNICS AND TECHNOLOGY |
Название |
Assessment of ecological safety of flotation
reagents in the process of hematite ores concentration |
Автор |
Yurlova N. A., Kayfadzhyan E. N., Shumskaya E. N., Poperechnikova O. Yu. |
Информация об авторе |
Author 1: Name & Surname: Yurlova N. A. Company: RIVS-Proekt LLC (Saint-Petersburg, Russia) Work Position: Main specialist Scientific Degree: Doctor of Biological Sciences Contacts: e-mail: rivsproject@rivs.ru
Author 2: Name & Surname: Kaifadzhyan E. A. Company: Mendeleev Institute for Metrology (Saint-Petersburg, Russia) Work Position: Senior Researcher Scientific Degree: Candidate of Engineering Sciences
Author 3: Name & Surname: Shumskaya E. N. Company: RIVS Science and Production Association (Saint-Petersburg, Russia) Work Position: Principal Researcher Scientific Degree: Candidate of Engineering Sciences Contacts: e-mail: rivs@rivs.ru
Author 4: Name & Surname: Poperechnikova O. Yu. Company: RIVS Science and Production Association (Saint-Petersburg, Russia) Work Position: Head of Production Research Subdivision
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Реферат |
RIVS Science and Production Association carries out a wide range of work aimed at improvement of iron ore dressing technology and equipment. The scope of work embraces flotation of magnetite concentrates toward their quality refinement and production of superconcentrates, and development of efficient technology for oxidized ferruginous quartzite dressing. Concentration of hematite ore uses cation amine-containing surface active agents (AC SAA). It is required to control the remaining content of highly toxic and ecologically hazardous AC SAA. Concentration of flotation agents was measured using the spectrophotometric method (simple, inexpensive but less selective) and the selective method of gas–liquid partition chromatography based on certified procedures. The industrial environmental monitoring advises to use the selective methods to estimate concentration of flotation agents, including calculation of effluents treated to standard quality. The article shows that desorption of AC SAA can run in pulp slurry, which results in higher concentration of AC SAA in the recycling water. However, in the course of time, AC SAA undergo chemical transformation and their content in the recycling water and liquid phase of tailings reduces. The process of AC SAA decomposition intensifies under higher temperature. |
Ключевые слова |
Hematite ore, flotation, amine-containing surface active agents, flotation agents, spectrophotometric method, gas–liquid partition chromatography method |
Библиографический список |
1. Bachurin B. A., Odintsova T. A., Petrova E. S. Fiziko-khimicheskie aspekty formirovaniya sostava otkhodov gorno-obogatitelnogo proizvodstva (Physical-chemical aspects of formation of waste composition of ore-dressing works). Gornyi Zhurnal = Mining Journal. 2013. No. 6. pp. 86–89. 2. Metodika vypolneniya izmereniya massovoy kontsentratsii reagenta, otnosyashchegosya k klassu kationaktivnykh poverkhnostno-aktivnykh veshchestv, soderzhashchikh v svoem sostave aminnuyu gruppu, yavlyayushchimsya osnovnym deystvuyushchim veshchestvom pri protsesse flotatsii zheleznykh rud (Procedure of measurements of mass concentration of reagent (belonging to cation-active surface-active aminogen group-containing substances), which is the basic active material in iron ore flotation process). Saint Petersburg, 2004. 11 p. (in Russian). 3. Metodika vypolneniya izmereniy soderzhaniya flotoreagenta v vodnoy srede metodom gazozhidkostnoy khromatografii (GZhKh) M-MVI-206-08, utverzhdennaya Obshchestvom s Ogranichennoy Otvetstvennosyu «Monitoring» (Procedure of measurements of content of flotation reagent in aqueous medium by gas-liquid chromatography method M-MVI-206-08 (М-МВИ-206-08), approved by LLC “Monitoring”). Saint Petersburg, 2008. 18 p. (in Russian). 4. Metodika vypolneniya izmereniy soderzhaniya flotoreagenta v tverdoy faze metodom gazozhidkostnoy khromatografii M-MVI-207-08, utverzhdennaya Obshchestvom s Ogranichennoy Otvetstvennosyu «Monitoring» (Procedure of measurements of content of flotation reagent in solid phase by gas-liquid chromatography method M-MVI-207-08 (М-МВИ-207-08), approved by LLC “Monitoring”). Saint Petersburg, 2008. 19 p. (in Russian). 5. Yurlova N. A. Ekologicheskie aspekty pri proektirovanii obektov i predpriyatiy gorno-dobyvayushchego kompleksa (Ecological aspects in the time of designing of objects and enterprises of mining complex). Gornyi Zhurnal = Mining Journal. 2010. No. 10. pp. 101–104. |
Полный текст статьи |
Assessment of ecological safety of flotation
reagents in the process of hematite ores concentration |