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ArticleName Mechanism of nickel oxides dissolving by sulphuric acid solutions in acid environment
ArticleAuthor Volkov L. V., Kalashnikova M. I.
ArticleAuthorData

Saint Petersburg State Polytechnical University

L. V. Volkov, Professor

 

Gipronickel Institute

M. I. Kalashnikova, Head of Laboratory of Hydrometallurgy, e-mail: MIKal@nikel.spb.ru

Abstract

Mechanism of nickel oxides dissolving by sulphuric acid has been proposed. The mechanism explains sharp acceleration of the process running at the solution redox potential of ~1.4 V created by the oxidants not participating in the reaction. In the above environment, reaction NiO dissolving takes place via formation and dissolution of NiOx (1 < x < 2). Values of the both reactions’ equilibrium potentials have been calculated as x functions, and values of their over-voltage have been defined according to the model of the reactions speed control by the stage of charge’ transfer through the interphase’ surface. The calculations have revealed that the reaction maximum speed is achieved at х = 1.4–1.6, which corresponds to redox potential of 1.4 V. Deviation of x meaning from 1.4–1.6 results in the reduction of the dilution reaction speed. That is why dissolving of NiO or NiO2 stoichiometric oxides runs at a lower speed.

keywords Nickel oxides, mechanism of dissolving, solutions, sulphuric acid, oxidation conditions, equilibrium potentials, rate of solution, charge transfer
References

1. Kalashnikova M. I., Volkov L. V., Keskinova M. V. Tsvetnye metally - Non-ferrous metals. 2011. No. 3. pp. 43–46.

2. Bogatskiy D. P. Zhurnal obshchey khimii - Journal of General Chemistry. 1951. Vol. XXI, issue I. pp. 3–10.

3. Fetter K. Elektrokhimicheskaya kinetika (Electrochemical Kinetics). Moscow, 1967. 856 pp.

4. Tyurin A. G. Termodinamika khimicheskoy i elektrokhimicheskoy ustoychivosti splavov : dis. … d-ra khim. nauk : 02.00.04 (Thermodynamics of chemical and electrochemical stability of the alloys : tesis ... Doctor of Chemical Sciences : 02.00.04). Chelyabinsk, 2008. 484 pp.

5. Pichugina N. M. Kinetika i mekhanizm rastvoreniya oksidov nikelya v kislykh sredakh : dis. … kand. khim. nauk : 02.00.01 (Kinetics and mechanism of dissolution of nickel oxides in acid media : thesis ... Candidate of Chemical Ssciences : 02.00.01). Moscow, 2003. 299 pp.

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