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PHYSICAL CHARACTERISTICS AND THEIR STUDY
Название Conductivity of vanadium, cobalt and niobium doped titania layers
Автор L. A. Balagurov, I. V. Kulermanov, A. F. Orlov, E. A. Petrova
Информация об авторе L. A. Balagurov, I. V. Kulermanov, A. F. Orlov, E. A. Petrova, OAO Giredmet.
Реферат
Special attention to the electric properties of titania is caused by its recent use for the manufacturing of various electronic devices. The temperature dependence of direct and alternating current conductivity of titania layers doped with vanadium, and also simultaneously by cobalt and niobium have been investigated. The layers were prepared by RF magnetron deposition in oxygen and argon atmospheres at a temperature of 550 °C and 2·10−2 Torr vacuum with a deposition velocity of 0.07 nm/s. We found that vanadium doped samples have conductivity dependencies typical of variable range hopping. The density of the localized states at the Fermi level was estimated. On the contrary, the conductivity of cobalt and niobium doped layers is caused by the tunnel conductivity with the thermal activation of the carriers between clusters, apparently cobalt ones. Thus, measurement of electrical resistance as a function of temperature is a fast and reliable technique for cluster detection in a material.
Ключевые слова Titania, vanadium, niobium, HF magnetron deposition, conductivity.
Библиографический список

1. Li, B. Review of recent progress in solid-state dye-sensitized solar cells / B. Li, L. Wang, B. Kang, P. Wang, Y. Qiu // Solar Energy Mater. Solar Cells. - 2006. - V. 90, N 5. - P. 549—573.
2. Janisch, R. Transition metal-doped TiO2 and ZnO — present status of the field / R. Janisch, P. Gopal, N. Spaldin // J. Phys: Condens. Matt. - 2005. − V. 17. — P. R657—R672.
3. Zaleska, A. Doped-TiO2: A review / A. Zaleska // Recent Pat. on Eng. - 2008. - V. 2, N 3. - P. 157—164.
4. Balachandran, U. Electrical conductivity in non-stoichiometric titanium dioxide at elevated temperatures / U. Balachandran, N. G. Eror // J. Mater. Sci. - 1988. - V. 23, N 8. - P. 2676—2682.
5. Belloch, J. M. Synthesis, characterization and semiconducting properties of solid solutions with rutile structure / J. M. Belloch, J. Isasi, M. L. Lopez, M. L. Veiga, C. Pico // Mater. Res. Bull. - 1994. - V. 29, N 8. - P. 861—869.
6. Matsumoto, Y. Room-temperature ferromagnetism in transparent transition metal-doped titanium dioxide / Y. Matsumoto, M. Murakami, T. Shono, T. Hasegawa, T. Fukumura, M. Kawasaki, P. Ahmet, T. Chikyow, S. Koshihara, H. Koinuma // Science. - 2001. - V. 291. - P. 854—857.
7. Shinde, S. R. Ferromagnetism in laser deposited anatase Ti1-xCoxO2-δ films / S. R. Shinde, S. B. Ogale, Das Sarma // Phys. Rev. B. - 2003. - V. 67, N 11. - P. 115211—115216.
8. Park, W. K. Semiconducting and ferromagnetic behavior of sputtered Co-doped TiO2 thin films above room temperature/W. K. Park, R. J. Ortega-Hertogs, J. S. Moodera, A. Punnoose, M. S. Seehra // J. Appl. Phys. - 2002. - V. 91, N 10. - P. 8093—8095.
9. Saragih, H. Co-doped TiO2 rutile thin films deposited by MOCVD method / H. Saragih, P. Arifin, M. Barmawi // «Nanoscience and Nanotechnology» ICONN‘06. Internat. Conf. - 2006. - P. 87—91.
10. Kim, D. H. Formation of Co nanoclusters in epitaxial Ti0.96Co0.04O2 thin films and their ferromagnetism / D. H. Kim, J. S. Yang, K. W. Lee, S. D. Bu // Appl. Phys. Lett. - 2002. - V. 81, N 13. - P. 2421—2423.

11. Kennedya, R. J. Hopping transport in TiO2:Co: A signature of multiphase behavio / R. J. Kennedya, P. A. Stampe, E. Hu, P. Xiong // Ibid. - 2004. - V. 84, N 15. - P. 2832—2834.
12. Furubayashi, Y. A transparent metal: Nb-doped anatase TiO2 / Y. Furubayashi, T. Hitosugi, Y. Yamamoto, K. Inaba // Ibid. - 2005. - V. 86, N 25. - P. 252101—252103.
13. Hitosugi, T. Ta-doped anatase TiO2 epitaxial film as transparent conducting oxide / T. Hitosugi, Y. Furubayashi, A. Ueda // Jap. J. Appl. Phys. Pt 2. - 2005. - V. 44. - P. L1063—L1065.
14. Hong, L. Electrical properties of transparent doped oxide films / L. Hong, K. Hiromitsu, Toshinobu // J. Sol-Gel Sci. and Technol. - 2000. - V. 19, N 1-3. - P. 529—532.
15. Serpone, N. Spectroscopic, photoconductivity and photocatalytic studies of TiO2 colloids: naked and with the lattice doped with Cr3+, Fe3+, and V5+ cations / N. Serpone, D. Lawless, J. Disdier // Langmuir. - 1994. - V. 10, N 3. - P. 643—652.
16. An, J. Visible light driven V-doped TiO2 photocatalyst and its photo oxidation of ethanol/ J. An, B. Kim, J. Jeong, D. Kim // J. Ceramic Processing Res. - 2005. - V. 6, N 2. - P. 163—166.
17. Kamegawa, T. Hydrothermal synthesis of visible light sensitive vanadium doped TiO2 photocatalysts and their applications for the degradation of isobutanol diluted in water / T. Kamegawa, K. Sugimura, K. Maki, K. Mori // J. Phys.: Conf. Ser. - 2009. - V. 165. - P. 012038—012040.
18. Sieradzka, K. Properties of nanocrystalline TiO2 : V thin films as a transparent semiconducting oxides / K. Sieradzka, J. Domaradzki, E. Prociow, M. Mazur, M. Lapinski // Acta Phys. Polonica A. - 2009. - V. 116. - P. 33—35.
19. Ohtomo, A. MgxZn1−xO as a II–VI widegap semiconductor alloy / A. Ohtomo, M. Kawasaki, T. Koida, K. Masubuchi, H. Koinuma, Y. Sakurai, Y. Yoshida, T. Yasuda, Y. Segawa // Appl. Phys. Lett. - 1998. - V. 72, N 19. - P. 2466—2468.
20. Mott, N. F. Electron Processes in Non-Crystalline Materials / N. F. Mott - Oxford: Clarendon Press, 1982.
21. Kao, K. Perenos elektronov v tverdykh telakh / K. Kao, V. KHuang - M. : Mir, 1984. - CH. 1. - S. 350.
22. Fromknecht, R. Lattice location and electrical conductivity in ion implanted TiO2 single crystals / R. Fromknecht, R. Auer, I. Khubeis, O. Meyer // Nucl. Instrum. and Meth. in Phys. Res. B. - 1996. - V. 120, N 1–4. - P. 252—256.
23. Poumellec, B. Electron transport in TiO2−x at intermediate temperatures 300 K < T < 1500 K / B. Poumellec, J. F. Marucco, F. Lagnel // Phys. status solidi A. - 1985. - V. 89, N 1. - P. 375—382.

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