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HEAVY NON-FERROUS METALS
Название Technology of integrated treatment of mine water with accompanying extraction of non-ferrous metals
DOI 10.17580/tsm.2017.12.03
Автор Kurdiumov V. R., Timofeev K. L., Lebed A. B., Maltsev G. I.
Информация об авторе

Centre for Studies, JSC “Uralelektromed”, Verkhnyaya Pyshma, Russia:

V. R. Kurdiumov, Manufacturing Engineer of Research Center, e-mail: kvr@elem.ru
K. L. Timofeev, Chief Hydrometallurgist of Engineering Department
G. I. Maltsev, Chief Specialist of a Centre for Studies

UMMC Technical University, Verkhnyaya Pyshma, Russia:

A. B. Lebed, Head of a Chair of Metallurgy

Реферат

Spent mines are the sources of water, contaminated by non-ferrous metals, manganese, iron, silicon, calcium, etc. The possible way of treatment of a weakly mineralized mine water with elevated contents of ions of nickel, manganese and hardness salts is ion exchange using Lewatit Monoplus TP 207 resin in combination with a chemical softening, microfiltration and disinfection. The laboratory studies of mine water treatment were carried out on the pilot plant with the flow rate of 5 dm3 per hour. The initial mine water has the following composition, mg/dm3: 9.8–11.4 Si; 1.8–2.30 Mn; 0.19–0.28 Ni; 53.8–73.0 Na; 0.02–0.20 Cu; 0.01–0.07 Zn; 0.01–0.06 Fe. At the same time, the total hardness is 7.5–8.4 mmol/dm3 and pH is 7.2–7.4. The following results of treated water composition were attained, mg/dm3: 8.1–9.9 Si; 0.005–0.009 Mn; < 0.005 for Ni; 102.0–167.0 Na; < 0.005 Cu; < 0.005 Zn; < 0.005 Fe. The total hardness is 2.0– 5.7 mmol/dm3 and pH is 6.5–8.3. The content of other impurities is below the detection limit. The treated mine water meets the quality requirements for potable water. The sulphuric acid regeneration of ionite was carried out after its saturation by non-ferrous metals. The obtained nickel and copper containing eluate may be used in technology of nickel and copper sulphate production.

Ключевые слова Non-ferrous metals, total hardness, mine water, ionite, water softening, sorption, ion-exchange, water treatment, potable water
Библиографический список

1. Mongayt I. L., Tekinidi K. D., Nikoladze G. I. Mine waters treatment. Moscow : Nedra, 1978. 173 p.
2. Milovanov L. V. Treatment and use of wastewaters of non-ferrous metallurgy enterprises. Moscow : Metallurgiya, 1971. 384 p.
3. Wolkersdorfer C., Bowell R. Contemporary reviews of mine water studies in Europe, part 2. Mine Water and the Environment. 2005. Vol. 24, No. 1. pp. 2–37.
4. Voron L. V., Lange L. R., Blagorazumova A. M. Problems of mine water treatment. Vestnik SibGIU. 2015. No. 2 (12). pp. 76–79.
5. Yonger P. L., Bawart S. A., Hedin R. S. Mine water: hydrology, pollution, remediation. Dodrecht : Kluwer Academic Publishers, 2002. 442 p.
6. Surzhko O. A., Okovitaya K. O., Baryshnikov A. V. Increasing of efficiency of mine waters deferization in the Eastern Donbass. Innovatsionnaya nauka. 2016. No. 9 (21). pp. 93–96.
7. Gusev N. N., Kaplunov Yu. V., Podsevalov A. N. Treatment of mine waters to the potable quality at liquidated mines. Gornyy informatsionno-analiticheskiy byulleten. 2010. No. 2. pp. 308–313.
8. Chernyy M. L. Sorption extraction of rare-earth and non-ferrous metals from mine waters and pulps : Dissertation … of Candidate of Engineering Sciences. Ekaterinburg, 2005. 139 p.
9. Chen G. Electrochemical technologies in wastewater treatment. Separation and Purification Technology. 2004. Vol 38, No. 1. pp. 11–41.
10. Figueroa L., Wolkersdorfer C. Electrochemical recovery of metals in mining influenced water: state of the art. An Interdisciplinary Response to Mine Challenges. Xuzhou : China University of Mining and Technology Press, 2014. pp. 627–631.
11. Pilipenko A. T., Goronovskiy I. T., Grebenyuk V. D. et al. Complex processing of mine waters. Kiev : Tekhnika, 1985. 183 p.
12. Kesieme U. K. Mine waste water treatment and acid recovery using membrane distillation and solvent extraction : PhD thesis. Melbourne, 2015. 94 p.
13. Isaev O. N., Suslenkov V. D. Mine waters treatment from oil and grease admixtures and suspended matters. Vestnik RUDN. 2004. No. 1. pp. 61–63.
14. Kharionovskiy A. A. Complex treatment of mine and pit waters from anthropogenic pollutions. Shakhty : Izdatelstvo YuRO AGN, 2000. 238 p.
15. Rudolf Hering. Chelatbildende lonenaustauscher. Moskau : Mir, 1971. 279 s.
16. Timofeev K. L. Sorption of heavy metals from drains of mining and metallurgical enterprises : Dissertation … of Candidate of Engineering Sciences. Ekaterinburg, 2013. 162 p.
17. SanPin 2.1.4.1074-01. Potable water. Hygienic requirements to water quality in centralized systems of drinking water supply. Quality control. Sanitary Rules and Regulations. Moscow, 2009.

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